Use of Biocides and Soy Oil in Preservative Treatment of Structural Flakeboard

Authors

  • Qun Fang
  • Yanyan Zhao
  • Quanben Du
  • Monlin Kuo

Keywords:

Flakeboard, preservative treatment, biocides, soy oil, brown-rot decay

Abstract

Many uses of structural wood composite panels require preservative treatment to increase decay resistance. The most cost-effective way to treat structural flakeboard is done during manufacturing, but it is difficult to accomplish because of incompatibility between adhesive resins and preservatives. The objective of this study was to evaluate physical properties and decay resistance of flakeboard made with phenolic wood adhesive resins blended with biocides dissolved in soybean oil. The blended phenolic adhesive resins contained equal parts of iodo-propynyl butyl carbamate, propiconazole, and tebuconazole. Hybrid poplar flakeboards were made at the combined biocide retention levels of 0, 0.51, 0.81, and 1.63 kg/m3. Results indicated that the strength and dimensional stability properties of flakeboard were not affected by the in-process preservative treatment. The biocides were stable and maintained their efficacy against decay after pressing boards at 200°C for 7 min. Boards treated with 1.63 kg/m3 biocides sustained 2.5% to 5.0% weight loss after exposing to the brown-rot fungus (Postia placenta) for 12 wk compared with over 27% weight loss of nontreated boards.

References

Acad M, Morrell JJ, Levien KL (1997) Effects of process variables on supercritical fluid impregnation of composites with tubeconazole. Wood Fiber Sci 29(3):282-290.nAmerican Society for Testing and Methods (1996a) Standard methods for evaluating the properties of wood-based fiber and particle panel materials. ASTM Standard D1037-96. ASTM, West Conshohocken, PA.nAmerican Society of Testing and Materials (1996b) Standard method of testing wood preservatives by laboratory soilblock cultures. ASTM Standard D-1413-99. ASTM, West Conshohocken, PA.nCanadian Standards Association (1993) CSA 0437 OSB and waferboard. CSA. Rexdale, Ontario, Canada.nHakkou M, Petrissans M, Gerardin P, Zoulalian A (2006) Investigation of the reasons of the increase for fungal durability of heat-treated beechwood. Polym Degrad Stab 91(2):393-397.nKnudson RM, Gnatowski MJ (1989) Chemically treated wood particle board. U. S. Patent 4,879,083.nKuo ML, Lan HF, Stokke DD (2006) Decay resistance of flakeboard bonded with protein-based resin containing biocides. Pages 344-348 in MNM Yusoff, KM Poh, MD Jantan, WA Ibrahim, M Saleh, R Rusli, R Hashim, J Kasim, PM Tahir, S Zakaria, eds, Proc, 8th Pacific Rim Bio-based Composites Symposium, 20-23 November 2006, Kuala Lumpur, Malaysia. Forest Research Institute Malaysia, Selangor Darul Ehsan, Malaysia.nKuo ML, Stokke DD, McNabb HS Jr. (1988) Microscopy of progressive decay of cottonwood by the brown-rot fungus Gloeophyllum trabeum. Wood Fiber Sci 20(4): 405-414.nLaks PE, Haataja BA, Palardy RD, Bianchini RJ (1988) Evaluation of adhesives for bonding borate-treated flakeboards. Forest Prod. J. 38(11/123):23-24.nLaks PE, Palardy RD (1993) Properties and process considerations for preservative-containing waferboards. Pages 12-17 in A. F. Preston, editor, Symposium on Protection of Wood-based Composite Products, Orlando, FL, May 1993. Forest Products Society, Madison, WI.nMurphy RJ (1994) Vapor phase treatment for wood products. Proc Wood Preservation in the '90s and Beyond, Proc No. 7308. Forest Products Society, Madison, WI.nOberdorfer G, Leichti RJ, Morrell JJ (2004) Determination of wood-based material during supercritical carbon dioxide treatment. Wood Fiber Sci 36(4):511-519.nSAS Institute Inc (1987) SAS/STAT guide for personal computers. Version 6 ed. SAS, Cary, NC.nSchmidt RL, Gertjejansen RO (1988) Trials of two powdered preservatives for phenol-formaldehyde and polymeric isocynate-bonded aspen structural composite board. Forest Prod J 38(3):19-21.nVick CB, DeGroot RC, Youngquist J (1990) Compatibility of nonacidic waterborne preservatives with phenol- formaldehyde adhesive. Forest Prod J 40(2):16-22.nVidrine C, Kamke FA, Morrell JJ, Preston A (2008) Preserving panels by furnish addition of copper compounds: Effects on panel properties. Proc American Wood Protection Association 104:135-145.nVidrine C, Kamke F, Preston A, Morrell JJ (2009) The effects of copper-based preservatives technologies on the resistance of aspen strandboards to biological degradation. Wood Fiber Sci 41(3):211-219.n

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Published

2013-10-18

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Research Contributions