Combustibility of Boron-Containing Fire Retardant Treated Bamboo Filaments
Keywords:
bamboo filament, boric acid, borax, heat release, smoke releaseAbstract
Abstract:
As an indoor decorative material, bamboo filaments should be treated with flame retardants for safe use. The effects of different treatment conditions on boron loading of flame retardants (boric acid/borax 1:1) in bamboo filaments were investigated by single factor experimental design. Furthermore, effects of boron-containing flame retardants on combustibility of bamboo filaments were evaluated by cone analysis. The results showed that boron loading in treated bamboo filaments increased distinctly as treatment duration, temperature, or solution concentration increased. Compared with untreated and ultraviolet (UV)-treated bamboo filaments, heat release decreased obviously in treated bamboo filaments with greater boron loading, heat rates were only 50% and 30% of untreated bamboo filaments and UV bamboo filaments, and the total amount of heat release was decreased by 39.7% and 56.5%, respectively. During the combustion process, boron-containing flame retardants had excellent smoke suppression efficacy and total smoke release was decreased by 86.1% and 91.1%, respectively. As a result, boron-containing flame retardants promote carbon residue production of treated bamboo filaments and decrease themass loss during fire.
References
Blasi CD, Branca C, Galgano A (2007) Flame retarding of
wood by impregnation with boric acid-pyrolysis products
and char oxidation rates. Polym Degrad Stabil
:752-764.
Enyu X, Minxiu Z (1988) Flame retardant science and application, 1st ed. National Defence Industry Press, Beijing.
GB (2012) 8624-12. Standard methods for classification
burning behavior of building materials and products.
China National Standardization Committee, Beijing, China.
ISO (2002) 5660-1. Reaction to fire tests-Heat release,
smoke production and mass loss rate-Part 1: Heat release
rate (cone calorimeter method). International Organization
for Standardization Committee, Geneva, Switzerland.
Jiang J, Yang Y, Li J (2011) Effect of three boron flame
retardants on thermal curing behavior of urea formaldehyde
resin. J Therm Anal Calorim105(1):223-228.
Lee SH, Wang SQ (2006) Biodegradable polymers/bamboo
fiber biocomposite with bio-based coupling agent.
Composites Part A 37(1):80-91.
Lei D, Wu L, Chen D (2004) Themodern furniture with raw
bamboo: A blend of tradition form and modern aesthetics.
Word Bamboo and Raton 2(4):41-43.
LeVan SL (1984) Chemistry of fire retardancy. The chemistry
of solid wood. Pages 531-532 in Rowell R, ed. Advances
in chemistry series 207. American Chemical Society,
Washington, DC.
Li J, Fang GZ, Li SJ, Wang QW (2012) Wood protection.
China Science Publication Organization, Beijing. 120 pp.
Liu S, Chu F, Yu W (2013) Properties of crushed bamboomat
composite treated by ammonium polyphosphate.
China Wood Industry 27(3):5-8.
Marosi G, Ma’rton A, Anna P (2002) Ceramic precursor
in flame retardant systems. Polym Degrad Stabil
:259-265.
Mukherjee GN, Ansuman D (2002) Mixed ligand complex
formation of Fe with boric acid and typical N-donor
multidentate ligands. J Chem Sci 114(3):163-174.
Nussbaum R (1988) The effect of low concentration fire
retardant impregnations on wood charring rate and char
yield. J Fire Sci 6:290-306.
Silvo H, Majda SS, Karin SK (2007) Flame retardant activity
of SiO2-coated regenerated cellulose fibres. Polym Degrad
Stabil 92:1957-1965.
Song S, Yang F, Sun Z (2014) The sliced bamboo winding
technology and processing technology. China Forest
Products Industry 41(3):34-36.
Taghiyari HR (2006) English for special purpose: Wood
and paper sciences and technology. Karafarinan Publication
Organization. 205 pp.
Terzi E, Kartal SN, Robert HW (2011) Fire performance
and decay resistance of solid wood and plywood treated
with quaternary ammonia compounds and common fire
retardants. Eur J Wood Wood Prod 69:41-51.
Uysal B, Ozciftci A (2004) The effects of impregnation
chemicals on combustion properties of laminated wood
material. Combust Sci Technol 176(1):117-133.
Wang QW (2000) FRW fire retardant for wood. PhD diss,
Northeast Forestry University, Harbin, China. Pages 95-110.
Wang QW, Li J, Winandy JE (2004) Chemical mechanism
of fire retardance of boric acid on wood. Wood Sci
Technol 38(5):375-389.
White RH, Dietenberger MA (1999) Fire Safety Design
and Evaluation, Chapter 17: Fire safety. Todays Or
Nurse 21(12):245-246.
Yalinkilic MK, Imamura Y, Takahashi M (1999) In situ
polymerization of vinyl monomers during comprehensive
deformation of wood treated with boric acid to decay boron
leaching. Forest Prod J 49:43-51.
Yang H, Chen G, Wang X (2007) Bamboo furniture and
ecological design. J Zhengzhou University of Light
Industry 8(4):73-75.
Yang W, Qing Y (2014) Effect of typical boron compounds
on the thermal degradation and combustion properties
of phyllostachys pubescen. J Therm Anal Calorim
(4):51-55.
Zhang H (2013) Research progress of modificated zinc
borate. China Rubber/Plastics Technol and Equip
:9-13.
Zhang Y (2011) The research on artitic design-expression
of the native bamboo. MS thesis, Hunan, China. 39-80 pp.
Zhao N, Lei D, Wu L (2010) Cultural and functional support
in designing of bamboo products. J. Bamboo Res
(2):52-58.
Zhu M, Huang J (2009) Synthesis of new bamboo fire
retardant. Hunan Forestry Sci Technol 36(1):34-36.
Downloads
Published
Issue
Section
License
The copyright of an article published in Wood and Fiber Science is transferred to the Society of Wood Science and Technology (for U. S. Government employees: to the extent transferable), effective if and when the article is accepted for publication. This transfer grants the Society of Wood Science and Technology permission to republish all or any part of the article in any form, e.g., reprints for sale, microfiche, proceedings, etc. However, the authors reserve the following as set forth in the Copyright Law:
1. All proprietary rights other than copyright, such as patent rights.
2. The right to grant or refuse permission to third parties to republish all or part of the article or translations thereof. In the case of whole articles, such third parties must obtain Society of Wood Science and Technology written permission as well. However, the Society may grant rights with respect to Journal issues as a whole.
3. The right to use all or part of this article in future works of their own, such as lectures, press releases, reviews, text books, or reprint books.