Moisture Dependence of Indentation Deformation and Mechanical Properties of Masson Pine (<i>Pinus Massoniana</i> Lamb) Cell Walls as Related to Microfibrilar Angle

Authors

  • Li Wanju
  • Wang Hankun
  • Wang Hao
  • Yu Yan

Keywords:

Wood, cell wall, mechanical properties, moisture content, microfibrillar angle, nanoindentation

Abstract

To better understand how microfibrillar angle (MFA) and moisture content influence the mechanical performances of wood at the cell wall level, the nanoindentation technique was used to measure the indentation modulus, hardness, indentation creep rate (ICR), residual plastic deformation (RPD), and elastic recovery deformation (ERD) of Masson pine (Pinus massoniana Lamb) wood cell walls with small (16°), medium (27°), and large (38°) MFA values at 5, 8, and 11% MC, respectively. The results show cell wall elastic modulus was negatively correlated to moisture content, but the specific trend was to some extent affected by the value of MFA. MFA has a negative influence on cell wall elastic modulus across the range of all tested moisture contents. Cell wall hardness decreased significantly with increase of moisture content for all three MFA values, whereas the effect of MFA was insignificant. RPD and ERD of cell walls responded differently to the change of moisture content and MFA. In general, RPD is more sensitive to moisture content than MFA, whereas ERD and ICR are more sensitive to MFA than the low moisture content range as defined in this study.

References

Burgert I, Keckes J, Frühmann K (2002) A comparison of two techniques for wood fiber isolation—Evaluation by tensile tests on single fibers with different microfibril angle. Plant Biol 4(1):9-12.nButterfield BG (1998) Microfibril angle in wood. Proc IAWA/IUFRO International Workshop on Significance of Microfibril Angle to Wood Quality, Univ. Canterbury, New Zealand. 410 pp.nCave ID (1966) Theory of X-ray measurement of microfibril angle in wood. Forest Prod J 16(10):37-42.nCave ID (1969) The longitudinal Young's modulus of Pinus radiate. Wood Sci Technol 3(1):40-48.nCave ID (1978) Modelling moisture-related mechanical properties of wood. Part I: Properties of the constituents. Wood Sci Technol 12(1):75-86.nCave ID, Walker JCF (1994) Stiffness of wood in fast-grown plantation softwoods: The influence of microfibril angle. Forest Prod J 44(5):43-48.nCousins WJ (1976) Elastic modulus of lignin as related to moisture content. Wood Sci Technol 10(1):9-17.nCousins WJ (1978) Young's modulus of hemicelluloses as related to moisture content. Wood Sci Technol 12(3): 161-167.nEhrnrooth EM, Kolseth P (1984) The tensile testing of single wood fibers in air and in water. Wood Fiber Sci 16(4):549-566.nElder T (2007) Quantum chemical determination of Young's modulus of lignin. Calculations on a β-O-4'model compound. Biomacromolecules 8(11):3619-3627.nGindl W, Gupta HS, Schöberl T, Lichtenegger HC, Fratzl P (2004) Mechanical properties of spruce wood cell walls by nanoindentation. Appl Phys A-Mater 79(8):2069-2073.nGindl W, Schöberl T, Keches J (2006) Structure and properties of pulp fiber-reinforced composite with regenerated cellulose matrix. Appl Phys A-Mater 83:19-22.nGindl W, Teischinger A (2002) Axial compression strength of Norway spruce related to structural variability and lignin content. Compos Part A-Appl S 33(12):1623-1628.nGroom LH, Mott L, Shaler SM (2002a) Mechanical properties of individual southern pine fibers. Part I: Determination and variability of stress-strain curves with respect to tree height and juvenility. Wood Fiber Sci 34(1):14-27.nGroom L, Shaler S, Mott L (2002b) Mechanical properties of individual southern pine fibers. Part III: Global relationships between fiber properties and fiber location within an individual tree. Wood Fiber Sci 34(2):238-250.nHogan CJ, Niklas KJ (2004) Temperature and water content effects on the viscoelastic behavior of Tilia americana (Tiliaceae) sapwood. Trees (Berl) 18(3):339-345.nKojima Y, Yamamoto H (2005) Effect of moisture content on the longitudinal tensile creep behavior of wood. J Wood Sci 51(5):462-467.nKoponen S, Toratti T, Kanerva P (1989) Modelling longitudinal elasticity and shrinkage properties of wood. Wood Sci Technol 23(1):55-63.nKretschmann DE, Green DW (1996) Modeling moisture content-mechanical property relationships for clear southern pine. Wood Fiber Sci 28(3):320-337.nLee SH, Wang SQ, Pharr GM, Xu HT (2007) Evaluation of interphase properties in a cellulose fiber-reinforced polypropylene composite by nanoindentation and finite element analysis. Compos Part A-Appl S 38(6):1517-1524.nNishino T, Takano K, Nakamae K (1995) Elastic modulus of the crystalline regions of cellulose polymorphs. J Polym Sci Pol Phys 33(11):1647-1651.nOliver WC, Pharr GM (1992) An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments. J Mater Res 7(6):1564-1583.nPage DH, El-Hosseiny F (1983) The mechanical properties of single wood pulp fibres. Part VI. Fibril angle and the shape of stress-strain cure. J Pulp Paper Sci 9(4):99-100.nReiterer A, Lichtenegger H, Tschegg S, Fratzl P (1999) Experimental evidence for a mechanical function of the cellulose microfibril angle in wood cell walls. Philos Mag 79(9):2173-2184.nReiterer A, Tschegg S (2002) The influence of moisture content on the mode I fracture behaviour of sprucewood. J Mater Sci 37(20):4487-4491.nSakurada I, Nukushina Y, Ito T (1962) Experimental determination of the elastic modulus of crystalline regions in oriented polymers. J Polym Sci, Polym Phys Ed 57(165): 651-660.nSalmén L (2004) Micromechanical understanding of the cell-wall structure. C R Biol 327(9):873-880.nWimmer R, Lucas BN (1997) Comparing mechanical properties of secondary wall and cell corner middle lamella in spruce wood. IAWA Journal 18(1):77-88.nYamamoto H, Kojima Y (2002) Properties of cell wall constituents in relation to longitudinal elasticity of wood. Part 1. Formulation of the longitudinal elasticity of an isolated wood fiber. Wood Sci Technol 36(1):55-74.nYu Y, Fei BH, Wang HK, Tian GL (2011) Longitudinal mechanical properties of cell wall of Masson pine (Pinus massoniana Lamb) related to different moisture contents by nanoindentation. Holzforschung 65(1):121-126.nYu Y, Jiang ZH, Tian GL (2009) Size effect on longitudinal MOE of microtomed wood sections and relevant theoretical explanation. For Stud China 11(4):243-248.n

Downloads

Published

2014-04-04

Issue

Section

Research Contributions