Using Benzylated Poplar as Adhesive in Manufacturing Wood-Based Panels

Authors

  • Qu Baoxue
  • Qin Tefu
  • Zhu Yanzhong
  • Chu Fuxiang

Keywords:

Benzylation, differential scanning calorimetry, mechanical property, poplar, wood-based board

Abstract

Benzylated poplar was prepared and its properties were characterized by Fourier transform infrared spectroscopy, a soften point test, and differential scanning calorimetry. This study reports on the enhanced thermoplasticity of benzylated poplar with its weight gain increased. Because of its thermoplasticity, benzylated poplar can be used instead of traditional adhesives to coat wood-based panels. Plywood fabricated with benzylated poplar had a bonding strength of 1.84 MPa and an average wood failure of 76.2%. Fiberboard containing 40% benzylated poplar had an internal bonding strength of 0.81 MPa, a modulus of rupture (MOR) of 45 MPa, a modulus of elasticity of 4900 MPa, and a density between 700 and 800 kg/m-3. Wheatstraw board containing 20% benzylated poplar had an internal bonding strength of 0.48 MPa, an MOR of 32 MPa, and a density between 0.5 and 0.6 g/cm-3.

References

EMB (1995) the third edition. Euro MDF Board industrial standard, Part II: Requirements for general purpose boards. European Association of Medium Density Fiberboard Manufacturers, Giessen, Germany.nEN (1993a) 317. Particleboards and fibreboards: Determination of swelling in thickness after immersion in water. European Committee for Standardization, Brussels, Belgium.nEN (1993b) 319. Particleboards and fibreboards: Determination of tensile strength perpendicular to the plane of the board. European Committee for Standardization, Brussels, Belgium.nEN (1993c) 310. Wood-based panels: Determination of modulus of elasticity in bending and of bending strength. European Committee for Standardization, Brussels, Belgium.nEN (2003) 312. Particleboards: Specifications. European Committee for Standardization, Brussels, Belgium.nGBT (2004) 9846.3. Plywood—Part 3: General specification for plywood for general use. Standardization Administration of the People's Republic of China, Beijing, China.nHassan S, Mohammadi RJ (2003) Chemical modification of beech wood. Iran Polym J 12(1):15-20.nHonma S, Okumura K, Yoshioka M, Shiraishi N (1992) Mechanical and thermal properties of benzylated wood. Pages 140-146 in Proc International Symp on Chemical Modification of Lignocellulosics, November 1992, Rotorua, New Zealand. FRI Bull 176.nJAS (2008) JPIC-EW.SE03-08. Plywood. Ministry of Agriculture, Forestry and Fisheries (MAFF), Tokyo, Japan.nKiguchi M (1992) Chemical modification of wood surfaces by etherification III-Some properties of self-bonded benzylated particleboard. Journal of the Japan Wood Research Society 38(2):150-158.nKiguchi M (1993) Chemical modification of wood surfaces by etherification IV—Benzylation with solvent-dilution and vapor-phase methods. Journal of the Japan Wood Research Society 39(1):80-85.nLi Y (2006) Preparation, structure and properties of benzylated wood and composite thereof. MS thesis, Huaqiao University, Guangzhou, Fujian, China. 96 pp.nMa L (2007) Plasticization of wood by benzylation. MS thesis, University of Idaho, Moscow, Idaho. 228 pp.nMohammadi RJ (2003) Plasticization of poplar wood by benzylation and acetylation. Journal of Science and Technologyh 27(B2):353-358.nQu B (2010) Study on cyanoethylation, benzylation of wood fiber material and their utilization. Doctor of Science thesis, Chinese Academy of Forestry, Beijing, China. 129 pp.nTeng L, Wang K, Guo G (2004) Modification of wood by benzylation under microwave radiation. Journal of Chemical Industry of Forest Products 38(1):21-24.nWan D, Luo X, Huang G, Zeng G (2005) Study on the modification of bagasse by benzylation. Forestry Science and Technology 30(3):57-59.nWang F, Li Z, Ai Z (2011) New research progress in fiberboard adhesives and their formaldehyde emission. Adhesion 10:68-71.nYoshioka M, Uehori Y, Toyosaki H, Hashimoto T, Shiraishi N (1992) Thermoplasticization of wood and its application. Pages 155-162 in Proc International Symp on Chemical Modification of Lignocellulosics. November 1992, Rotorua, New Zealand (FRI Bull 176).nZhang P, Yao Y, Zhang G, Liu Q (2012) Survey of formaldehyde pollution of decorative board manufacturing enterprises. Zhejiang Journal of Preventive Medicine 24(1):40-41.n

Downloads

Published

2013-01-10

Issue

Section

Research Contributions