Temperature Effect on Diffusion Coeficient in Drying Wood
Keywords:
Wood drying, drying temperature, moisture diffusion, activation energy, simulationAbstract
The effect of drying temperature on unsteady-state moisture diffusion was studied by drying small, nearly green. 25-mm-thick specimens of yellow-poplar (Liriodendron tulipifera L.) and red oak (Quercus sp.) at four temperatures (32.2, 43.3, 54.4, and 65.6°) and at two successive equilibrium moisture contents (10 and 5% EMC). That the moisture diffusion through wood is an activated process was indicated by the fact that the plots of the logarithm of diffusion coefficient versus the reciprocal of absolute temperarature were largely linear. However, the calculated activation energies (4195 cal/mol for yellow-poplar, 6166 cal/mol for red oak when dried to 10% EMC) differed greatly, were of low magnitude, and were possibly related to the specific gravity of the wood.References
Atkins, P. W. 1982. Physical chemistry, 2nd ed. The University Press, Cambridge, England. 1095 pp.nBarrer, R. M. 1941. Diffusion in and through solid. The University Press, Cambridge, England. 464 pp.nBiggerstaff, T. 1965. Drying diffusion coefficients in wood: As affected by temperature. Forest Prod. J. 15: 127-134.nBramhall, G. 1979. Sorption diffusion in wood. Wood Science 12:3-13.nChen, Y., E. T. Choong, and D. M. Wetzel. 1995. Evaluation of diffusion coefficient and surface emission coefficient by an optimization technique. Wood Fiber Sci. 27(2):178-182.nChoong, E. T. 1965. Diffusion coefficients of softwoods by steady state and theoretical methods. Forest Prod. J. 15(1):21-27.nComstock, G. L. 1963. Moisture diffusion coefficients in wood as calculated from adsorption, desorption, and steady state data. Forest Prod. J. 13:97-103.nCrank, J. 1975. The mathematics of diffusion, 2nd ed. Oxford University Press, Oxford, England. 414 pp.nHart, C. A. 1988. A user's manual for a family of simulation of moisture sorption in wood. Dept. of Wood and Paper Science. North Carolina State University, Raleigh, NC. 44 pp.nHunter, A. J. 1992. On the activation energy of diffusion of water in wood. Wood Sci. Technol. 26:73-82.nMcNamara, W. S., and C. A. Hart. 1971. An analysis of interval and average diffusion coefficients for unsteady-state movement of moisture in wood. Wood Science 4(1):37-45.nNelson, R. M., Jr. 1991. Heats of transfer and activation energy for bound water diffusion in wood. Wood Sci. Technol. 25:193-202.nPrager, S., and E. S. Long. 1951. Diffusion of hydrocarbons in polyisobutylene. J. Am. Chem. Soc. 73:4072-4075.nRasmussen, E. F. 1961. Dry kiln-operator's manual. Forest Products Lab, Forest Service, USDA. 197 pp.nSiau, J. F., F. Bao, and S. Avramidis. 1986. Experiments in nonisothermal diffusion of moisture in wood. Wood Fiber Sci. 18(1): 84-89.nSimpson, W. T. 1993. Determination and use of moisture diffusion coefficient to characterize drying of northern red oak. Wood Sci. Technol. 27:409-420.nSkaar, C. 1958. Moisture movement in beech below the fiber saturation point. Forest Prod. J. 8:352-357.nSkaar, C., and M. Babiak. 1982. A model for bound-water transport in wood. Wood Sci. Technol. 16:123-138.nStamm, A. J. 1959. Bound-water diffusion into wood in the fiber direction. Forest Prod. J. 9(1):27-31.nStamm, A. J. 1964. Wood and cellulose science. The Ronald Press Company, New York, NY. 549 pp.nStamm, A. J., and R. M. Nelson, Jr. 1961. Comparison between measured and theoretical diffusion coefficient for southern pine. Forest Prod. J. 11:536-543.nTarkow, H., and A. J. Stamm. 1960. Diffusion through air-filled capillaries of softwoods: I. Carbon dioxide. Forest Prod. J. 10(5):247-250.nYao, J. 1966. A new approach to the study of drying diffusion coefficients of wood. Forest Prod. J. 16(6):61-69.n
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