A Sealed Pressing System and its Use to Explore the Ammonia Plasticization of Natural Fiber Mats

Authors

  • Mohammed Jahangir A. Chowdhury
  • Philip E. Humphrey

Keywords:

Natural fiber mats, ammonia plasticization, sealed pressing, gas injection

Abstract

The effectiveness of gaseous ammonia as a softening agent for natural fiber and particle composite mats has been examined. A miniature digitally controlled sealed pressing system with provision for chemical injection and removal through permeable graphite platens was developed for this and other purposes. The pressing system is described, along with its use to examine the softening action of anhydrous ammonia on 97-mm-diameter thermomechanical pulp (TMP) mats. This was done principally in terms of treatment time (0 to 900 s) and partial pressure (0.0345 to 0.7444 MPa). Ammonia applied at moderate partial pressures (0.42 MPa) was found to rapidly penetrate and soften (within 4 s) mats compressed to a density of 525 kg m-3 at near-room temperatures (29°C). The results suggest that judicious injection of ammonia in sealed pressing arrangements may provide an attractive alternative to our current dependency on heat- and moisture-induced softening in conventional composite pressing methods—both in terms of production speed and providing the ability to optimally sequence rheological and adhesion mechanisms

References

Ashby, M. F. 1995. Materials selection in mechanical design. Butterworth Heinemann, London, UK.nBariska, M., C. Skaar, and R. W. Davidson. 1969. Studies of the wood-anhydrous ammonia system. Wood Science 2(2):65-72.nBarry, A. J., F. C. Peterson, and A. J. King. 1936. X-ray studies of reactions of cellulose in non-aqueous systems. Part I. Interaction of cellulose and liquid ammonia. J. Am. Chem. Soc. 55:333.nBolton, A. J., and P. E. Humphrey. 1991. The permeability of wood-based composites. Part I. A review of the literature and some unpublished work. Holzforschung 48 (supl):95-100.nChowdhury, M. J. A. 1999. Sealed consolidation of natural fiber composites with chemical reactant injection and removal. Doctoral thesis. Department of Wood Science and Engineering, Oregon State University, Corvallis, OR.nDavidson, R. W. 1968. Plasticizing wood with anhydrous ammonia. Report by New York State University, College of Forestry at Syracuse University, Syracuse, NY.nDavidson, R. W., and W. G. Baumgardt. 1970. Plasticizing wood with ammonia—a progress report. Forest Prod. J. 20(3):19-25.nHaselein, C. R. 1998. Numerical simulation of pressing wood-fiber composites, Ph.D. thesis, Department of Forest Products, Oregon State University, Corvallis, OR.nHumphrey, P. E. 1994. Engineering composites from orientated fiber networks: A strategy. Pages 2-8. in Proc. Second Pacific Rim Bio-based Composites Symposium. University of British Colombia, November 6-9, Vancouver, Canada.nKalninsh, A. I., V. N. Sergeeva, and Z. N. Kreitsberg. 1967. Effect of 25% aqueous solution of ammonia on wood. Pages 7-13 in T. A. Darzinsh, ed. Modifikatsiya drevering, Academy of Sciences of the Latvin SSR Institute of the Chemistry of Wood. Izdatelstvo Zinatne, Riga, (in Russian).nRen, S. 1992. Thermo-hygro-rheological behavior of materials used in the manufacture of wood-based composites. Ph.D. thesis, Department of Forest Products, Oregon State University, Corvallis, OR.nSchuerch, C. 1952. The solvent properties of liquids and their relation to the solubility, swelling, isolation and fractionation of lignin. J. Am. Chem. Soc. 54:50-61.nSchuerch, C. 1963. Plasticizing wood with liquid ammonia. Ind. and Eng. Chem. 55:39.nSchuerch, C. 1964. Principles and potential of wood plasticization. Forest Prod. J. 14(9):377-381.nStamm, A. J. 1955. Swelling of wood and fiberboards in liquid ammonia. Forest Prod. J. 5(6):413-416.nThoemen, H., and P. E. Humphrey. 2003. Modeling the continuous pressing process for wood-based composites. Wood Fiber Sci. 35 (3):456-468.n

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Published

2007-06-05

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Research Contributions