Lignin Distribution in Soda-Oxygen and Kraft Fibers as Determined by Conventional Electron Microscopy

Authors

  • Shiro Saka
  • Richard J. Thomas
  • Josef S. Gratzl

Keywords:

Soda-oxygen pulping, kraft pulping, Kappa number, lignin distribution, fiber, SEM-EDXA, KMnO<sub>4</sub> staining, ultrathin section, direct carbon replica

Abstract

The lignin distribution in loblolly pine (Pinus taeda L.) fibers produced by soda-oxygen and kraft pulping was investigated by electron microscopy of KMnO4 stained ultrathin sections and direct carbon replicas. A more extensive delignification of outer layers of fibers was found in soda-oxygen pulps than in kraft pulps. However, kraft pulping is more effective than soda-oxygen pulping in removing lignin from the lumen side of fibers. These observations were in good agreement with an earlier study of the lignin distribution within pulp fibers performed with SEM-EDXA technique.

References

Bentum, A. L. K., W. A. Cote, A. C. Day, and T. E. Timell. 1969. Distribution of lignin in normal and tension wood. Wood Sci. Technol. 3(3):218-231.nBland, D. E., R. C. Foster, and A. F. Logan. 1971. The mechanism of permanganate and osmium tetroxide fixation and the distribution of lignin in the cell wall of Pinus radiata. Hoizforschung 25(5):137-143.nClark, I. T. 1962. Determination of lignin by hydrofluoric acid. Tappi 45(4):310-314.nCote, W. A., Z. Koran, and A. C. Day. 1964. Replica techniques for electron microscopy of wood and paper. Tappi 47(8):477-484.nFergus, B. J., and D. A. I. Goring. 1970. The distribution of lignin in birch wood as determined by ultraviolet microscopy. Holzforschung 24(4):118-124.nFergus, B. J., A. R. Procter, J. A. N. Scott, and D. A. I. Goring. 1969. The distribution of lignin in spruce wood as determined by ultraviolet microscopy. Wood Sci. Technol. 3(2):117-138.nHepler, P. K., D. E. Fosket, and E. H. Newcomb. 1970. Lignification during secondary wall formation in Coleus: An electron microscope study. Am. J. Bot. 57(1):85-96.nKerr, A. J., and D. A. I. Goring. 1976. Kraft pulping of pressure-refined fibers. Reactivity of exposed middle lamella lignin. Svensk Papperstidn. 79(1):20-23.nKutscha, N. P., and J. M. Schwarzmann. 1975. The lignification sequence in normal wood of balsam fir (Abies balsamea). Holzforschung 29(3):79-84.nLuft, J. H. 1961. Improvements in epoxy resin embedding methods. J. Biophys. Biochem. Cytol. 9(2):409-414.nNorberg, P. H. 1969. Electron microscope studies of the morphology of fibers subjected to different chemical pulping conditions. Svensk Papperstidn. 72(18):575-582.nParham, R. A. 1974. Electron microscopy of pulp and paper. Wood Sci. 6(3):245-255.nParham, R. A., and W. A. Cote. 1971. Distribution of lignin in normal and compression wood of Pinus taeda L. Wood Sci. Technol. 5(1):49-62.nPhillips, R. B., and D. C. McIntosh 1975. Microscopic characterization of paper and fiber properties of linearboard yield soda-oxygen/alkali and kraft pulps. Tappi 58(2):76-79.nProcter, A. R., and W. Q. Yean and D. A. I. Goring. 1967. The topochemistry of delignification in kraft and sulphite pulping of spruce wood. Pulp Paper Mag. Can. 68(9):T445-453.nSachs, I. B., I. T. Clark, and J. C. Pew. 1963. Investigation of lignin distribution in the cell wall of certain woods. J. Polym. Sci. Part C(2):203-212.nSaka, S., R. J. Thomas, and J. S. Gratzl. 1978. Lignin distribution. Determination by energy-dispersive analysis of X rays. Tappi 61(1):73-76.nWood, J. R., and D. A. I. Goring. 1973. The distribution of lignin in fibers produced by kraft and acid sulphite pulping of spruce wood. Pulp Paper Mag. Can. 74(9):117-121.n

Downloads

Published

2007-06-28

Issue

Section

Research Contributions