Short-Term Creep as Related to Cell-Wall Crystallinity

Authors

  • M. Lofty
  • M. El-osta
  • R. W. Wellwood

Abstract

X-ray diffraction technique was utilized to determine the relative degree of crystallinity of some coniferous wood tissues, namely Douglas-fir (Pseudotsuga menziesii (Mirb.) Franco) normal and compression wood, and normal wood of Sitka spruce (Picea sitchensis (Bong.) Carr.) and western hemlock (Tsuga heterophylla (Raf.) Sarg.). Total creep values were available from a previous study for test samples matched with those used for determining degree of crystallinity. Creep response was measured using two constant loads corresponding to predetermined initial strain levels of 3,000 (A) and 6,000 (B) μinches/inch.

The relative degrce of cell-wall crystallinity was found to be linearly correlated (inversely) with short-term creep. Results of this investigation also revealed that cell-wall crystallinity contributes up to 67.2 and 51.8% of the total variability in creep response for samples tested at constant loads corresponding to strain levels (A) and (B), respectively. It is suggested that a relatively high degree of crystallinity increases the rigidity of cell wall, which thereby resists excessive creep deformation.

References

Berkley, E. E., and T. Kerr. 1946. Structure and plasticity of undried cotton fibers. Ind. Eng. Chem. 38(3):304-309.nBinotto, A. P., W. K. Murphey, and B. E. Cutter. 1971. X-ray diffraction studies of cellulose from bark and wood. Wood and Fiber 3(3): 179-181.nChow, S.-Z. 1969. Molecular rheology of coniferous wood tissues. Unpublished Ph.D. Thesis, Faculty of Forestry, Univ. B.C. 142 p.nEl-osta, M. Lotfy M. 1971. Influence of some characteristics of coniferous wood tissues on short-term creep. Unpublished Ph.D. Thesis, Faculty of Forestry, Univ. B.C. 147 p.nChow, S.-Z., and R. W. Wellwood. 1972. Short-term creep as related to microfibril angle. Wood and Fiber 4(1):26-32.nHarada, H., and T. Taniguchi. 1971. Cell-wall organization of tracheids of springwood and summerwood. Bull. Kyoto Univ. For. No. 42:205-209.nHearle, J. W. S. 1958. A fringed fibril theory of structure in crystalline polymers. J. Polymer Sci. 28:432-435.nHearle, J. W. S. 1963. The fine structure of fibers and crystalline polymers. I. Fringed fibril structure. J. Appl. Polymer Sci. 7:1175-1192.nHeyn, A. N. J. 1965. Crystalline state of cellulose in fresh and dried mature cotton fiber from unopened bolls as studied by X-ray diffraction. J. Polymer Sci. A3:1251-1265.nHill, R. L. 1967. The creep behavior of individual pulp fibers under tensile stress. Tappi 50(8):432-440.nHolzer, W. F., and H. F. Lewis. 1950. The characteristics of unbleached kraft pulp from western hemlock, Douglas fir, western red cedar, loblolly pine and black spruce. VII. Comparison of summerwood and springwood of Douglas fir. Tappi 33(2): 110-112.nIngersoll, H. G. 1946. Fine structure of viscose rayon. J. Appl. Phys. 17(11):924-939.nJentzen, C. A. 1964. The effect of stress applied during drying on some of the properties of individual pulp fibers. Tappi 47(7):412-418.nKouris, M., H. Ruck, and S. G. Mason. 1958. The effect of water removal on the crystallinity of cellulose. Can. J. Chem. 37:931-948.nLee, C. L. 1961. Crystallinity of wood cellulose fibers studied by X-ray methods. For. Prod. J. 11(2):108-112.nLindgren, P. H. 1958. X-ray orientation investigations on some Swedish cellulose materials. Arkiv for Kemi 12(38):437-452.nMark, H. 1940. Intermicellar hole and tube system in fiber structure. J. Phys. Chem. 44(6):764-788.nMurphey, W. K. 1963. Cell-wall crystallinity as a function of tensile strain. For. Prod. J. 13(4): 151-155.nNelson, R. 1961. The use of holocellulose to study cellulose supermolecular structure. J. Polymer Sci. 51:27-58.nNelson, R., and C. M. Conrad. 1948. Effect of grinding on the crystallinity of cellulose fibers, as indicated by the acid-hydrolysis and other techniques. Text. Res. J. 18(3):155-164.nNelson, R., and E. F. Schultz, Jr. 1963. X-ray diffractogram of cotton: Effect of sample weight and other variables. Text. Res. J. 33(7):515-520.nParham, R. A. 1971. Crystallinity and ultrastructure of ammoniated wood. Wood and Fiber 2(4):311-320.nRåndy, B. G. 1958. The fine structure of cellulose fibrils, p. 52-82. In F. Bolam (ed.), Fundamentals of papermaking fibers. First Tech. Sect. British Paper and Board Makers' Association (London).nSquire, G. B. 1967. Examination of cellulose-lignin relationship within coniferous growth zones. Unpublished Ph.D. Thesis, Faculty of Forestry, Univ. B.C. 140 p.nTimell, T. E. 1965. Wood and bark polysac-charides, p. 127-156. In W. A. Cçté (ed.), Cellular ultrastructure of woody plants. Syracuse Univ. Press.nTripp, V. W., R. S. Orr, H. M. Zhfle, and C. M. Conrad. 1958. Some relationships between supermolecular structure and mechanical behavior of native and chemically modified cotton cellulose. Text. Res. J. 28(5):404-447.nWard, K., Jr. 1950. Crystallinity of cellulose and its significance for the fiber properties. Text. Res. J. 20(6):363-372.nWilson, J. W., and R. W. Wellwood. 1965. Intra-increment chemical properties of certain western Canadian species, p. 551-559. In W. A. Cçté (ed.), Cellular ultrastracture of woody plants. Syracuse Univ. Press.nZiegler, G. A. 1969. The effect of thermal energy and tensile loads parallel to the grain on the rheological properties of Pseudotsuga menziesii (Mirb.) Franco. Unpublished M.Sc. Thesis, Dept. Wood Sci. Tech., Pennsylvania State Univ. 58 p.nSegal, L., J. J. Greely, A. E. Martin, Jr., and L. M. Conrad. 1959. An empirical method for estimating the degree of crystallinity of native cellulose using X-ray diffractometer. Text. Res. J. 29(10):786-794.nSisson, W. A. 1938. X-ray diffraction behavior of cellulose derivatives. Ind. Eng. Chem. 30(5):530-537.n

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2007-06-05

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Research Contributions