Interactions Between Lignin and Cellulose in Organic Liquid and Saline Density Gradient Columns

Authors

  • John M. Harkin
  • John R. Obst

Keywords:

<i>Populus tremuloides</i>, <i>Picea sitchensis</i>, ball-milled wood, enzyme lignin, cotton, Avicell

Abstract

Despite significant differences in their densities, lignin and carbohydrates associate so strongly, even in physical mixtures, that no separation takes place in liquid density gradient columns. Ball-milled cellulose, lignin, and wood exhibit much higher densities in salt gradients than in organic liquid gradients indicating penetration of the saline solutions into voids or "free volume" in the polymers that are inaccessible to organic liquids.

References

Björkman, A. 1956. Studies on finely divided wood. Part 1. Extraction of lignin with neutral solvents. Sven. Papperstidn. 59:477-485.nCaulfield, D. F., and R. A. Steffes. 1969. Water-induced recrystallization of cellulose. Tappi 52:1361-1366.nDobbins, R. J. 1970. The role of water in cellulose-solute interactions. Tappi 53:2284-2290.nFergus, B. J., and D. A. I. Goring. 1970. Distribution of lignin in birchwood as determined by ultraviolet microscopy. Holzforschung 24: 118-124.nGrushnikov, O. P., and N. N. Shorygina. 1970. The present state of the problem of lignin-carbohydrate bonds in plant tissues. Russ. Chem. Rev. 39(8):684-694.nHermans, P. H. 1949. Physics and chemistry of cellulose fibers. Elsevier, New York. Pp. 197-213.nKellogg, R. M., and F. F. Wangaard. 1969. Variation in the cell-wall density of wood. Wood Fiber 1(3): 180-204.nOster, G., and M. Yamamoto. 1963. Density gradient techniques. Chem. Rev. 63:257-268.nPew, J. C., and P. Weyna. 1962. Fine grinding, enzyme digestion, and the lignin-cellulose bond in wood. Tappi 45:247-256.nRuck, H. 1967. Zur Dichtebestimmung der Cellulose. Das Papier 21:697-713.nSarkanen, K. V., and C. H. Ludwig. 1971. Lignins; occurrence, formation, structure and reactions. Wiley-Interscience, New York.nStamm, A. J. 1969. Correlation of structural variations of lignins with their specific gravities. Tappi 52:1498-1502.nTobolsky, A. V. 1960. Properties and structures of polymers. Wiley, New York. Pp. 61-65.n

Downloads

Published

2007-06-05

Issue

Section

Research Contributions