Sem X-Ray Analysis of Pentachlorophenol in Treated Wood: <i>Research Note</i>

Authors

  • Joseph B. Zicherman

Keywords:

Pseudotsuga menziesii, Cellon process, energy-dispersive X-ray analysis (EDXA), preservative distribution, (SEM), wood preservation

Abstract

The distribution of pentachlorophenol preservative in cell walls of Douglas-fir pressure treated either by the Cellon2 process, or with pentachlorophenol in light petroleum oil, was studied using scanning electron microscopy-energy dispersive X-ray analysis (SEM-EDXA). Results indicate that both preservative treatments caused pentachlorophenol to be deposited throughout the gross structure of the wood and within cell walls as well. Extraction with benzene failed to remove the pentachlorophenol deposited within cell walls, as indicated by SEM-EDXA results, although the preservative had been applied with nonpolar organic carriers.

References

Arganbright, D. G. 1973. Interactions between pentachlorophenol solutions and wood. Wood Fiber 4(4):252-258.nChou, C. K., J. A. Chandler, and R. D. Preston. 1973. Microdistribution of metal elements in wood impregnated with a copper-chromearsenic preservative as determined by analytical electron microscopy. Wood Sci. Technol. 7(2):151-160.nDavies, G. W. 1968. Electron microscopy and cell-wall porosity. Appita 21(4):117-121.nExley, R. R., B. G. Butterfield, and B. A. Meylan. 1974. Preparation of wood specimens for the scanning electron microscope. J. Micros. 101(1):21.nGray, R. L., and W. A. Côté, Jr. 1974. SEM/EDXA as a diagnostic tool for wood and its inclusions. IAWA Bull. 3:6-11.nGreaves, H. 1974. Electron probe X-ray analysis of selected anatomical structures in copper-chrome-arsenic-treated wood. Wood Sci. 7(2): 164-168.nHess, D., R. Falk, and D. Bayer. 1975. The influence of specimen topography on X-ray microanalysis element mapping. Am. J. Bot. 62 (3): 246-253.nLeutritz, J. 1971. Stabilization of pentachlorophenol as indicated by extraction from wood samples with different solvents. Proc. Am. Wood Pres. Assoc. 67(198-202).nPetty, J. A., and R. D. Preston. 1968. Electron probe microanalysis of metals in cell walls of conifer wood treated with preservatives. Holzforschung 22(6):174-177.nResch, H., and D. G. Arganbright. 1971. Location of pentachlorophenol by electron microprobe and other techniques in Cellon-treated Douglas-fir. For. Prod. J. 21(1):38-43.nRudman, P. 1966. Studies in wood preservation. Holzforschung 20(2):60-67.nRuss, J. L. 1974. X-ray microanalysis in the biological sciences. J. Submicro. Cytol. 6:55-79.nWalters, C. S., and W. A. Côté. 1960. The distribution of pentachlorophenol in the micro-structure of basswood. Holzforschung 14(6):183-189.nWilcox, W. W. 1975. Micro-bioassay of pentachlorophenol within wood cell walls. For. Prod. J. 25(10):37-43.nWilcox, W. W., and N. Parameswaran. 1974. Method for electron microscopical demonstration of pentachlorophenol. Holzforschung 28(4):153-155.n

Downloads

Published

2007-06-05

Issue

Section

Research Contributions