The Effects of Copper-Based Preservative Technologies on the Resistance of Aspen Strandboards to Biological Degradation

Authors

  • Cheney Vidrine
  • Frederick Kamke
  • Alan Preston
  • Jeffrey J. Morrell

Keywords:

Oriented strandboard, OSB, copper ammine, zinc borate, DCOI, isothiazolone, tebuconazole, durable composites, mold resistance, aspen, <i>Populus tremuloides</i>

Abstract

Mold and decay resistance of aspen strandboards treated with various copper-based preservative systems were evaluated in laboratory tests. Five copper-based chemicals or zinc borate were blended into the aspen furnish at three retention levels. Tebuconazole or 4,5-dichloro-2-N-octyl-4-isothiazolin-3-one (DCOI) were added as cobiocides to selected copper-based treatments. Panels were inoculated with four common molds and subjected to high temperature and humidity for 8 wk according to AWPA Standard E24. Most panels experienced extensive mold growth, but panels treated with DCOI had marked resistance to attack as did combinations of copper-based preservatives and DCOI. Panels were also assessed for decay resistance in a laboratory soil-block test against the brown-rot fungus Gloeophyllum trabeum or the white-rot fungus, Trametes versicolor, according to AWPA Standard E10. All preservatives reduced weight losses caused by G. trabeum or T. versicolor below 10%, except for micronized copper hydroxide or DCOI alone. The four other copper-based preservatives performed well independently and with the addition of DCOI or tebuconazole. The results suggest that incorporating combinations of copper-based preservative systems with organic cobiocides improved decay and mold resistance of aspen-oriented strandboard.

References

Acda MN, Morrell JJ, Levien KL (1996) Decay resistance of composites following supercritical fluid impregnation with tebuconazole. Mater Organismen 30(4):293-300.nAWPA (2004a) A7-04. Standard for wet ashing procedures for preparing wood for chemical analysis. AWPA Book of Standards, Birmingham, AL.nAWPA (2004b) A9-01. Standard method for analysis of treated wood and treating solutions by X-ray spectroscopy. AWPA Book of Standards, Birmingham, AL.nAWPA (2004c) A21-00. Standard method for the analysis of wood and wood treating solutions by inductively coupled plasma emission spectrometry. AWPA Book of Standards, Birmingham, AL.nAWPA (2004d) A28-05. Standard method for determination of propiconazole and tebuconazole in wood, in waterborne formulations and in treating solutions by HPLC. AWPA Book of Standards, Birmingham, AL.nAWPA (2004e) A30-00. Standard method for the determination of 4,5 dichloro-2-N-octyl-4-isothiazolin-3-one (RH-287) in wood by high performance liquid chromatography (HPLC). AWPA Book of Standards, Birmingham, AL.nAWPA (2004f) E10-06. Standard method of testing wood preservatives by laboratory soil-block cultures. AWPA Book of Standards, Birmingham, AL.nAWPA (2007) E24-06. Standard method of evaluating the resistance of wood product surfaces to mold growth. AWPA Book of Standards, Birmingham, AL.nClausen CA, Yang VW (2005) Azole-based antimycotic agents inhibit mold on unseasoned pine. Int Biodeterior Biodegradation 55:99-102.nFogel JL, Lloyd JD (2002) Mold performance of some construction products with and without borates. Forest Prod J 52(2):38-43.nGardner DJ, Tascioglu C, Wålinder MEP (2003) Wood composite protection. American Chemical Society, Washington, DC. Pages 399-419.nGoroyias GJ, Hale MD (2000) Effect of point of preservative addition on the mechanical and physical properties of strandboard treated with Tanalith 3485. Document No IRG/WP 00-40152. The International Research Group on Wood Preservation, Stockholm, Sweden.nKirkpatrick JW, Barnes HM (2006) Copper naphthenate treatments for engineered wood composite panels. Biores Technol 97(15):1959-1963.nKumar S, Morrell JJ (1993) Improved composites from chemically modified particles. Pages 33-37 in Proc International Union of Forestry Research Organization (IUFRO) Symposium on the Protection of Wood-Based composite Products. Forest Products Society, Madison, WI.nLaks PE (1999) The past, present, and future of preservative-containing composites. Pages 151-158 in Proc The International Particleboard/composite Materials Symposium, Pullman, WA.nLaks PE, Palardy RD (1990) The development of borate-containing flakeboard. Pages 76-79 in Proc The International Conference on Wood Protection with Diffusible Preservatives. Forest Products Society, Madison, WI.nLaks PE, Palardy RD (1992) Factors that affect the performance of preservative-containing wafer-based composites. Pages 163-171 in Proc Pacific Rim Bio-Based composite Symposium, Rotorua, New Zealand.nLaks PE, Richter DL, Larkin GM (2002) Fungal susceptibility of interior commercial building panels. Forest Prod J 52(5):41-44.nLeightley LE, Nicholas DD (1990) In ground performance of wood treated with a substituted isothiazolone. Document No IRG/WP 3612. The International Research Group on Wood Preservation, Stockholm, Sweden.nManning MJ, Laks PE (1996) Zinc borate—A preservative treatment for composites. Pages 123-133 in Proc Seventeenth Annual Meeting of the Canadian Wood Preservation Association, Vancouver, BC.nMorrell JJ (2004) Mold on treated wood. American Wood Protection Association, Vancouver, BC, Canada. Pages 84-87.nMorris PI, Clark JE, Minchin D, Wellwood R (1999) Upgrading the fungal resistance of OSB. Document No IRG/WP 99-40138. The International Research Group on Wood Preservation, Stockholm, Sweden.nMurphy RJ, Turner P (1989) A vapour phase preservative treatment of manufactured wood based board materials. Wood Sci Technol 23(3):273-279.nPaul W, Ohlmeyer M, Leithoff H, Boonstra MJ, Pizzi A (2006) Optimising the properties of OSB by a one-step heat pre-treatment process. Holz Roh Werkst 64(3):227-234.nPreston AF, Fowlie DA, Archer KJ (2003) Dimensionally stable wood composites and methods for making them. US Patent 6569540(09/550027).nSAS Institute (2005) SAS/STAT® 9.1.3. Charlotte, NC.nSchmidt EL (1991) A resin-compatible copper naphthenate to preserve aspen composites. Forest Prod J 41(5):31-32.nSchmidt EL, Gertjejansen R (1988) Trials of two powdered preservatives for phenol-formaldehyde-bonded and polymeric-isocyanate-bonded aspen structural composite board. Forest Prod J 38(3):19-21.nTolley MP, Laks PE, Fears R (1998) Evaluation of chlorpyrifos and fungicides alone and in combination for control of insects and fungi in wood and wood composites. Document No IRG/WP 98-30187. The International Research Group on Wood Preservation, Stockholm, Sweden.nVidrine C, Kamke FA, Morrell J, Preston A (2008) Preserving panels by furnish addition of copper compounds: Effects on panel properties. InProc American Wood Protection Association 104:135-145.nWilliams GR, Lewis DA (1989) Observations on the colonization of freshly-felled timber treated with prophylactic chemicals by mould and sapstain fungi. Document No IRG/WP 1394. The International Research Group on Wood Preservation, Stockholm, Sweden.n

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Published

2009-07-16

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Research Contributions