Particleboard From Rubber Wood Flakes with Polymeric MDI Binder
Keywords:
Particleboard, polymeric MDI, wood flakes, binderAbstract
The use of rubber wood (Hevea brasiliensis) flakes for particleboard with polymeric diisocyanate (pMDI) as a binder was investigated. The effects of binder content in surface/core layers, cure temperature, cure time, and flake moisture on the properties of rubber wood particleboards were studied. The properties of the particleboard were compared with those of phenol-formaldehyde (PF) binder. The particleboard prepared from rubber wood flakes with pMDI binder gave high quality particleboards that had durability under severe conditions, low water absorption and thickness swelling, and a high modulus of rupture, modulus of elasticity, and internal bond strength. Moreover, pMDI binder could be cured at low temperatures, within a short time, and the binder consumption was small. The scanning electron micrographs of the rubber wood particleboard prepared from the high moisture content flakes showed the best, very tight packing characteristics.References
Akers, L. E. 1966. Particleboard and handbook, Vol. 4. Blakie & Sons, London, UK. P. 172.nCanadian Standards Association. 1978. Standard Test Methods for Mat-Formed Wood Particleboards and Waferboard. CSA Standard, CAN 3-01880.0-M78. 32 pp.nChen, R., and Q. Wu. 1994. Modified lignosulfonate as adhesive. J. Appl. Poly. Sci. 52:437-443.nDeutsche Norm. 1990. Flat press particleboard for use in building construction: concepts, requirements, testing and inspection. DIN 68763. 8 pp.nDix, B., and R. Marutzky. 1989. Modification of diisocyanate-based particleboard and plywood glues with natural polymers: polyphenols, carbohydrates and proteins. Pages 229-241 in M. J. Comstock, ed. Adhesive from renewable resource. American Chemical Society, Washington, D.C.nFranke, J., M. Kappe, K. Recker, H. Reiff, H. D. Ruprecht, and H. I. Sachs. 1994. Polyurethane (PUR) systems and polyisocyanates as starting materials for binders. Pages 615-628 in G. Oertel, ed. Polyurethane handbook. Hanser Publisher, New York, NY.nHolfinger, M. S., A. H. Conner, L. F. Lorenz, and C. G. Hill, Jr. 1993. Difurfuryl diisocyanates: New adhesives derived from renewable resources. J. Appl. Poly. Sci., 49:337-344.nThai Industrial Standard. 1989. Standard for Flat Pressed Particleboards: Medium Density. TIS 876-2532. 30 pp.nWendler, S. L., and C. E. Frazier. 1996. The effects of cure temperature and time on the isocyanates-wood adhesive bondline by 15N CP/MAS NMR. Int. J. Adhesion and Adhesive 16:179-186.nWood, G. 1990. IC1 Polyurethane, 2nd ed. John Wiley & Sons, New York, NY. P. 364.nYoungquist, J. A. 1992. The role of matrix, fiber and interface, Pages 383-401 in J. L. Vigo and B. J. Kinzig, eds. Composite applications, VCH Publisher, New York, NY.n
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