Effect of Process Variables on Supercritical Fluid Impregnation of Composites with Tebuconazole
Keywords:
Composites, particleboard, plywood, waferboard, flakeboard, fiberboard, tebuconazole, pressure treatment, supercritical fluids, carbon dioxideAbstract
This study examines the effects of pressure, temperature, and treatment time on supercritical fluid impregnation of such composites as plywood, particleboard, flakeboard, and medium-density fiber-board. Carbon dioxide with methanol as a cosolvent was used as the supercritical fluid, with tebuconazole as the biocide. Biocide distribution, as measured by extraction and analysis, generally increased with pressure, temperature, and treatment time, although the retentions sometimes decreased at the highest pressure tested (4500 psig). In general, biocide retentions were far above those required for fungal protection, and the distribution was more uniform than that found with conventional pressure treatments. The results suggest that supercritical fluid impregnation represents a simple method for impregnating composites with biocides without the permanent damage typical of other treatment systems.References
Acda, M., J. J. Morrell, and K. L. Levien. 1997. Effects of supercritical fluid treatments on physical properties of wood-based composites. Wood Fiber Sci. 29(2): 121-130.nAmerican Wood-Preservers' Association. 1994. Standard methods for analysis of wood and solutions for propiconazole by HPLC. Standard A23. In AWPA Book of Standards, Stevensville, MD.nDeppe, H. J. 1970. The protection of sheet material against water and decay. J. Inst. Wood Sci. 5(3):41-45.nEckert, C. A., J. G. Alsten, and T. Stoicos. 1986. Supercritical fluid processing. Environ. Sci. Technol. 20: 319-325.nFilippi, R. P. 1982. CO2 as solvent: Application to fats, oils, and other materials. Chem. Ind. 390-393.nGründlinger, R., and Exner, O. 1990. Tebuconazole-a new triaozole fungicide for wood preservation. Document No. IRG/WP 3629. International Research Group on Wood Preservation, Stockholm, Sweden.nHall, H. J., R. O. Gertjejansen, E. L. Schmidt, C. G. Carl, and R. C. DeGroot. 1982. Preservative treatment effects on mechanical and thickness swelling properties of aspen waferboard. Forest Prod. J. 32(11/ 12): 19-26.nHoyer, G. C. 1985. Extraction with supercritical fluids: Why, how and so what? ChemTech 15:440-448.nJunsophonsri, S. 1994. Solubility of biocides in pure and modified supercritical carbon dioxide. M.S. thesis, Oregon State University, Corvallis, OR.nKreber, B., P. E. Humphrey, and J. J. Morrell. 1993. Effect of polyborate pre-treatment on the shear strength development of phenolic resin to Sitka spruce bonds. Holzforschung 47:398-402.nKrukonis, V. J. 1988. Processing with supercritical fluids: Overview and applications. B. A. Charpentier and M. R. Sevenants, eds. Supercritical Fluid Extraction and Chromatography. Techniques and Applications. ACS Symp. Ser. 366:27-43. American Chemical Society, Washington, DC.nLaks, P. E., B. A. Haatala, R. D. Palardy, and R. J. Bianchini. 1988. Evaluation of adhesive for bonding borate-treated flakeboards. Forest Prod. J. 38(11/12): 23-24.nMarentis, R. T. 1988. Steps to developing a commercial supercritical carbon dioxide processing plant. B. A. Charpentier and M. R. Sevenants, eds. Supercritical Fluid Extraction and Chromatography. Techniques and Applications. ACS Symp. Ser. 366. American Chemical Society, Washington, DC.nMatson, D. W., and R. D. Smith. 1989. Supercritical fluid technologies for ceramic processing applications. J. Am. Ceram. Soc. 72:871-881.nMitchoff, M. E., and J. J. Morrell. 1991. Preservative treatment of plywood panels from the Pacific Northwest. Forest Prod. J. 41(9):11-17.nMorrell, J. J., K. L. Levien, E. Sahle Demessie, S. Kamar, S. Smith, and H. M. Barnes. 1993. Treatment of wood using supercritical fluid processes. Proc. Can. Wood Preserv. Assoc. 14:6-25.nMurphy, R. J., and P. Turner. 1989. A vapour phase preservative treatment of manufactured wood based board materials. Wood Sci. Technol. 23:273-279.nNeter, J., W. Wasserman, and M. H. Kutner. 1990. Applied linear models: Regression, analysis of variance, and experimental design. 3rd ed. Richard D. Irwin, Inc., Boston, MA.nSahle Demessie, E. 1994. Deposition of chemicals in semi-porous solids using supercritical fluid carriers. Ph.D. thesis, Oregon State University, Corvallis, OR. 301 pp.nSmith, S. M., E. Sahle Demessie, J. J. Morrell, K. L. Levien, and H. Ng. 1993. Supercritical fluid (SCF) treatment: Its effect on bending strength and stiffness of ponderosa pine sapwood. Wood Fiber Sci. 25:119-123.nVick, C. B. 1990. Adhesion of phenol-formaldehyde resin to waterborne emulsion preservative in aspen veneer. Forest Prod. J. 40(11/12):25-30.nVick, C. B., R. C. DeGroot, and Y. Youngquist. 1990. Compatibility of nonacidic waterborne preservatives with phenolic formaldehyde adhesive. Forest Prod. J. 40(2):27-32.n
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