Wood Propionylation in the Presence of Catalysts

Authors

  • Jian-Zhang Li
  • Takeshi Furuno
  • Sadanobu Katoh

Keywords:

Propionylation, catalyst, catalytic effect, catalyst loading, color difference

Abstract

Effects of potassium and sodium salts as catalysts on propionylation of wood and on the color change of propionylated wood have been investigated. It was found that potassium acetate, sodium acetate, sodium propionate, and sodium thiosulfate as catalysts were effective for propionylation of wood, and the catalyst loadings (CLs) of them had an effect on weight percent gains. The color of propionylated wood catalyzed with potassium acetate, sodium acetate, or sodium propionate changed very slightly, while sodium thiosulfate-catalyzed wood changed greatly with the increase of CL. Otherwise, potassium sulfate and sodium sulfate showed little or no catalytic effect, and sodium tetraborate decahydrate showed a negative catalytic effect on propionylation of wood.

References

Arni, P. C., J. D. Gray, and R. K. Scougall. 1961. Chemical modification of wood 2. Use of trifuluroacetic acid as a catalyst for acetylation of wood. J. Appl. Chem.11:163-170.nBaird, B. R. 1969. Dimensional stabilization of wood by vapor phase chemical treatments. Wood Fiber1(1):54-63.nBeckers, E. P. J., and H. Militz. 1994. Acetylation of solid wood: Initial trials on lab and semi-industrial scale. Second Pacific Rim Bio-Based Composites Symposium, Vancouver, BC. Pp. 125-134.nClermont, L. P., and F. Bender. 1957. The effect of swelling agents and catalysts on acetylation of wood. Forest Prod. J.7(5):167-170.nGoldstein, I. S., E. B. Jeroski, A. E. Lund, J. F. Nielson; and J. M. Weaver. 1961. Acetylation of wood in lumber thickness. Forest Prod. J.11(8):363-370.nHill, C. A. S., and D. Jones. 1996a. The dimensional stabilisation of corsican pine sapwood by reaction with carboxylic acid anhydrides. The effect of chain length. Holzforschung50(5):457-462.nHill, C. A. S., and D. Jones. 1996b. A chemical kinetics study of the propionic anhydride modification of corsican pine (1). Determination of activation energies. J. Wood Chem. Technol.16(3):235-247.nHill, C. A. S., and D. Jones. 1999. Dimensional changes in corsican pine sapwood due to chemical modification with linear chain anhydrides. Holzforschung53(3):267-271.nImamura, Y., and K. Nishimoto. 1987. Some aspects on resistance of acetylated wood against biodeterioration. Wood Research74:33-44.nKumar, S., S. P. Singh, and M. Sharma. 1979. Effect of acetylation on permeability of wood. J. Timber Dev. Assoc. India25(3):5-9.nLi, J.-Z., T. Furono, S. Katoh, and T. Uehara. 2000. Wood modification by anhydrides without solvents or catalysts. J. Wood Sci.46(3):215-221.nOhkoshi, M., A. Kato, and N. Hayashi. 1997. 13C-NMR analysis of acetyl groups in acetylated wood I. Acetyl groups in cellulose and hemicellulose. Mokuzai Gakkaishi43(4):327-346.nPeterson, M. D., and R. J. Thomas. 1978. Protection of wood from decay fungi by acetylation—An ultrastructural and chemical study. Wood and Fiber10(3):149-163.nRowell, R. M., A. Tillman, and R. Simonson. 1986. A simplified procedure for the acetylation of hard wood and soft wood flakes for flakeboard production. J Wood Chem. Technol.6(3):427-448.nSadachi, M. 1989. Acetylated wood. Wood Industry44(11):28-31 (in Japanese).nTarkow, H. 1959. A new approach to the acetylation of wood. Report on file at Forest Prod. Lab., Madison WI.nYano, H., M. Norimoto, and T. Yamada. 1986. Changes in acoustical properties of Sitka spruce due to acetylation. Mokuzai Gakkaishi32(12):950-995.n

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Published

2007-06-05

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Research Contributions