Dynamic Wettability Properties of Single Wood Pulp Fibers and Their Relationship to Absorbency

Authors

  • Kevin T. Hodgson
  • John C. Berg

Keywords:

Wetting, contact angle, dynamic wettability, Wilhelmy technique, absorbency, pulp fibers, Washburn theory, self-sizing, fluff pulp, penetration absorption, wicking flow, imbibition

Abstract

The Wilhelmy technique is used to measure dynamic wetting properties of single wood pulp fibers. Several different fiber types are examined, differing both in species and processing conditions. It is found that there are significant differences in water wettability of these fibers because of varying fiber surface chemistry. The compilation of a "dynamic wettability profile" for complex materials such as pulp fibers is advocated in order to characterize more fully the behavior of these materials in wetting situations. The bulk absorbency performance of three-dimensionally random pads of these fibers is found to be directly related to the initial advancing contact angles of single fibers. The measurement of single fiber wetting properties allows the separation of structural factors from surface chemical factors in considering the absorbency of a random network.

References

Aberson, G. M. 1970. The water absorbency of pads of dry, unbonded fibers. TAPPI STAP 8:282-307.nAbson, D. 1985. Fluff performance II: Self-sizing of Douglas fir fluff pulp. Weyerhaeuser Company Technical Report (041-9406).nAdamson, A. W. 1960. Physical chemistry of surfaces. Interscience Pub. Inc., New York. Pp. 27-28.nBack, E. L. 1965. Evaluation of liquid penetration into sorbing papers. Sven. Papperstidn. 68:614-617.nBerg, J. C. 1986. The use and limitations of wetting measurements in the prediction of adhesive performance. Pages 23-44 in L. Salmen et al., eds. Composite systems from natural and synthetic polymers. Elsevier, Amsterdam.nBorgin, K. 1959. The properties and the nature of the surface of cellulose. II: Cellulose in contact with water. Experimental results and their interpretation. Norsk. Skogind. 13:429-442.nCollins, G. E. 1947. A surface tension method for measuring the perimeters of fibres and the contact angles of liquids against fibres. J. Text. Inst. 38:T73-T77.nDaugherty, T. H. 1981. Dynamic wetting of single pulp fibers. M.S. thesis, University of Washington, Seattle, WA.nEverett, D. H. et al. 1977. Kinetics of capillary imbibition by fibrous materials. Pages 519-536 in Fibre-water interactions in papermaking: Symposium proceedings, BPBIF. Clowes, London, England.nFoote, J. E. 1939. A method for the measurement of the angle of contact formed between a liquid surface and a fiber and the application of this and swelling data to pore diameter measurements. Paper Trade J. Tappi Section. October: 40-48.nGraef, P. A. 1980. Cause of unacceptable oven-aged absorbency in Pacific fluff pulp. Weyerhaeuser Company Technical Report (041-7001).nGraef, P. A. 1981. Removal of extractives from Pacific fluff pulp. Weyerhaeuser Company Technical Report (014-6116).nGraef, P. A. 1986. Personal communication, Weyerhaeuser Company.nGrindstaff, T. H. 1969. A simple apparatus and technique for contact-angle measurements on small-denier single fibers. Textile Res. J. 39:958-962.nHoffman, R. L. 1975. A study of the advancing interface: I. Interface shape in liquid-gas systems. J. Colloid Interface Sci. 50(2):228-241.nJohnson, R. E., and R. H. Dettre. 1964. Contact angle hysteresis III. Study of an idealized heterogeneous surface. J. Phys. Chem. 68:1744.nJones, W. C., and M. C. Porter. 1967. A method for measuring contact angles on fibers. J. Colloid Interface Sci. 24:1-3.nKlungness, J. H. 1981. Measuring the wetting angle and perimeter of single wood pulp fibers: A modified method. Tappi 64(12):65-66.nLee, S. B., and P. Luner. 1972. The wetting and interfacial properties of lignin. Tappi 55(1):116-121.nLucas, R. 1918. Über das Zeitgesetz des Kapillaren Aufstiegs von Flussigkeiten. Kolloid-Z. 3: 15-22.nLuner, P., and M. Sandell. 1969. The wetting of cellulose and wood hemicelluloses. J. Polymer Sci.: Part C. 28:115-142.nMartinis, S. et al. 1981. Absorption of liquids by dry fiber networks. Tappi Annual Mtg. Preprint No. 7-3, Chicago. Pp. 1-8.nMiller, B. 1985. Experimental aspects of fiber wetting and liquid movement between fibers. Pages 121-147 in P. K. Chatterjee, ed. Absorbency. Elsevier, Amsterdam.nMiller, B., and R. A. Young. 1975. Methodology for studying the wettability of filaments. Textile Res. J. 45:359-365.nOkagawa, A., and S. G. Mason. 1977. Capillarography: A new surface probe. Pages 581-586 in Fibre-water interactions in paper-making: Symposium proceedings, BPBIF. Clowes, London, England.nSimmonds, F. A. 1934. Capillary rise of water in fibrous sheets and possible applications. Tech. Assoc. Pap. 17:401-403.nSwanson, J. W., and S. Cordingly. 1959. Surface chemical studies on pitch: II. The mechanism of the loss of absorbency and development of self-sizing in papers made from wood pulps. Tappi 42(10):812-819.nWashburn, E. W. 1921. The dynamics of capillary flow. Phys. Rev. 17(3):273-282.nWilhelmy, J. 1863. Über die Abhängigkeit der Kapillaritäts-Konstanten des Alkohols von Substantz und Gestalt des Benetzten Festen Korpers. Ann. Physik 119:177-217.nWise, E. C., and E. C. John. 1952. Wood chemistry, 2nd ed., Reinhold, New York.nYoung, R. A. 1976. Wettability of wood pulp fibers—Applicability of methodology. Wood Fiber 8(2): 120-128.n

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Published

2007-06-22

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Research Contributions