Southern Pine Wood and Strands Impregnated with Low Levels of Butanetetracarboxylic Acid as Stabilizing Agent for Oriented Strandboard
Keywords:
Butanetetracarboxylic acid, acid wood stabilization, dimensionally stable oriented strandboardAbstract
Southern pine wood specimens were impregnated with butanetetracarboxylic (BTCA) acid at 1.0-5.0% levels using a vacuum/pressure method and hot-pressing at 150°-210°C in the radial direction. The acid treatments gave anti-swelling efficiency (ASE) values up to 57% in an exhaustive first water-soak cycle. The ASE values were higher in the radial than tangential direction, and higher for irreversible than reversible components. Laboratory strandboards made with wood strands impregnated with 0.5°-1.0% BTCA levels under vacuum showed ASE values of up to 53%, but internal bond and modulus of elasticity and rupture values decreased somewhat excessively. The strength values of boards were modest, higher than the minimum industry requirements for commodity-type oriented strandboard. The various effects of BTCA on wood and board properties were discussed. Use of BTCA at less than 0.5% level and optimization of hot-pressing and resin binder and wax levels may result in a method of manufacturing oriented strandboard with significantly improved dimensional stability.References
American Plywood Association. APA. 1992. Performance standards for wood-based structural-use panels. PS2-92. 7011, Tacoma, WA. 28 pp.nAmerican Wood-Preservers' Association. 1988. AWPA standards. AWPA. M10-77. Woodstock, MD. P. 2.nCanadian Standards Association (CSA). 1993. Standards on OSB and Waferboard. CSA 0437 0-93. 178 Rexdale Boulevard, Rexdale, Ontario, Canada.nCaulfield, D. F. 1994. Ester crosslinking to improve wet performance of paper using multifunctional carboxylic acids, butanetetracarboxylic and citric acid. Tappi J.77(3):205.nFang, G. Z., Y. Z. Cui, and D. L. Chang. 1998. Fixation of heavy compression deformation of wood treated with polycarboxylic acids. China Wood Industry12(2):1619.nForest Products Laboratory. 1999. Wood handbook-wood as an engineering material. Gen. Tech. Rep. FPL-GTR-113. USDA, Forest Service, Madison, WI. 463 pp.nGoldstein, I. S., E. B. Jeroski, A. E. Lund, J. F. Nielson, and J. W. Weaver. 1961. Acetylation of wood in lumber thickness. Forest Prod J.11(8):363-370.nGomez, B. J., M. Westin, R. Torgilsson, P. O. Olesen, and R. Simonson. 1999. Composites made form acetylated lignocellulosic fibers of different origin. Part II. The effect of nonwoven fiber mat composition molding ability. Holz Roh-Werkst.57(3):178-184.nHon, D. N. S., and A. P. Bangi. 1996. Chemical modification of juvenile wood. Part 1. Juvenility and response of southern pine OSB flakes to acetylation. Forest Prod J.46(7-8):73-78.nHumphrey, P. E. 1982. Physical aspects of wood particle-board manufacture. Ph.D. Dissertation, University of North Wales, Bangor, UK.nHsu, W. E., W. Schwald, J. Schwald, and J. A. Shields. 1988. Chemical and physical changes required for producing dimensionally stable wood-based composites. J. Wood Sci. Technol.22:281-289.nInoue, M., M. Norimoto, M. Tanahashi, and R. M. Rowell. 1993. Steam or heat fixation of compressed wood. Wood Fiber Sci.25(3):224-235.nPeyer, S. M., M. P. Wolcott, and D. J. Fenoglio. 2000. Reducing moisture swell of densified wood with carboxylic acid resin. Wood Fiber Sci.32(4):520-526.nORTEC Inc., 505 Gentry Memorial Hwy., Easley, SC. 29640.nRoffael, E. 1987. Drying of pine particles and the effect on the strength of particleboards. Pages 361-381 in Proc. Washington State University Particleboard Symposium No. 21, Washington State University, Pullman, WA.nRowell, R. M., and W. D. Ellis. 1978. Determination of the dimensional stabilization of wood using the water soak method. Wood Fiber Sci.10(2):104-111.nSalmen, L. N. 1982. Temperature and water induced softening behavior of wood fiber based materials. Ph.D. Dissertation, Dept. of Paper Technology, The Royal Institute of Technology, Stockholm, Sweden.nSeborg, R. M., H. Tarkow, and A. J. Stamm. 1953. Effect of heat upon the dimensional stabilization of wood. Forest Prod J.3(3):59-67.nStamm, A. 1. 1964. Wood and cellulose science. Ronald Press Co., New York, NY, 549 pp.nTeal, W. B. 1994. An alternative approach to drying OSB strands. Pages 159-174 in Proc Washington State University Particleboard Symposium No. 28, Washington State University, Pullman, WA.nWan, H., and M. G. Kim. 2006. Southern pine wood and strands impregnated with low molecular weight phenolformaldehyde resin for stabilization of oriented strandboard (in press).nYang, C. Q. 1993. Infrared spectroscopic studies of the cyclic anhydride as the intermediate for the ester crosslinking of cotton cellulose by polycarboxylic acids. I. Identification of the cyclic anhydride intermediate. J. Polymer Sci. Part A: Polymer Chem31:1187-1193.nYang, C. Q., and B. A. K. Andrews. 1991. Infrared spectroscopic studies of the non-formaldehyde durable press finishing of cotton fabrics by use of polycarboxylic acids. J. Polymer Sci. Part A: Polymer Chem43:1609-1616.nYang, C. Q., and X. Wang. 1996. Infrared spectroscopic studies of the cyclic anhydride as the intermediate for the ester crosslinking of cotton cellulose by polycarboxylic acids. II. Comparison of different polycarboxylic acids. J. Polymer Sci. Part A: Polymer Chem34:1573-1580.nYang, C. Q., and X. Wang. 1997. Infrared spectroscopic studies of the cyclic anhydride as the intermediate for the ester crosslinking of cotton cellulose by polycarboxylic acids. III. Molecular weight of a crosslinking agent. J. Polymer Sci. Part A: Polymer Chem35:557-564.nZhou, Y. J., P. Luner, and P. Caluwe. 1995. Mechanism of crosslinking of paper with polyfunctional carboxylic acids. J. Polymer Sci. Part A: Polymer Chem58:1523-1534.n
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