Wood Sorption Fractality in the Hygroscopic Range. Part II. New Model Development and Validation
Keywords:
Water, sorption, isotherm, fractal dimension, internal surfaceAbstract
The sorption isotherms of mature sapwood and heartwood from two softwood species were obtained experimentally. The data were used for the determination of how their fractal values change with an increase in moisture content using the Hao-Avramidis model developed in the past, and for the substantiation of a new fractal polynomial sorption equation based mainly on the fractal parameter D, assuming D being the dominant control parameter of sorption at higher sorption regions. The new sorption theory considered both the molecular layering stage at low humidities and the non-layering or fractal sorption stages at high humidities. Its good curve-fitting behavior justified the assumption that the state dynamics of the sorbed water were stepwise or locative instead of smooth, and three or four steps were identified.References
Brunaner, S., P. H. Emmett, and E. Teller. 1938. Adsorption of gases in multilayer. J. Am. Chem. Soc.60:309-319.nHao, B. 1997. Moisture sorption characteristics of five B.C. softwoods. Directed Study Report. Department of Wood Science, The University of British Columbia, Vancouver, BC, Canada.nHao, B. 2002. Fractal geometry of wood internal surfaces in the hygroscopic range. Ph.D. thesis, Department of Wood Science, The University of British Columbia, Vancouver, BC, Canada.nHao, B., and B. Avramidis. 2001. Wood sorption fractality in the hygroscopic range, part I. Evaluation of a modified classic BET model. Wood Fiber Sci.33(1):119-125.nHartley, I. D. 1994. Characterization of water in wood below the fiber saturation point. Ph.D. thesis, The University of British Columbia, Department of Wood Science, Vancouver, BC, Canada.nHartley, I. D., and S. Avramidis. 1993. Analysis of the wood sorption isotherm using clustering theory. Holzforschung47(2):163-167.nHartley, I. D., F. A. Kamke, and H. Peemoeller. 1992. Cluster theory for water sorption in wood. Wood Sci. Technol.26(2):83-99.nKelsey, K. 1957. The sorption of water vapor by wood. Aust. J. Appl. Sci.8(1):42-54.nSimpson, W. 1973. Predicting equilibrium moisture content of wood by mathematical models. Wood Fiber5(1):41-49.nSiau, J. F. 1984. Transport processes in wood. Springer-Verlag, Berlin, Heidelburg, New York.nSiau, J. F. 1995. Wood: Influence of moisture content on wood properties. Virginia Polytechnic Institute and State University, Blacksburg, VA. 245 pp.nStamm, A. J. 1964. Wood and cellulose science. Ronald Press, New York, NY. 550 pp.n
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