Effect of Extractives on Water Sorption and Durability of Wood-Plastic Composites

Authors

  • Jae-Woo Kim
  • David P. Harper
  • Adam M. Taylor

Keywords:

Wood—plastic composites, extractives, mechanical properties, water sorption, fungal durability

Abstract

Wood—plastic composites (WPCs) were made from isotactic polypropylene and extracted and unextracted flours of one of four different wood species. WPCs made with extracted wood flour had lower mechanical properties than unextracted WPCs with the exception of pine WPCs. For all of the species except pine, WPCs made with extracted wood flours showed higher moisture sorption and thickness swelling characteristics. Higher levels of fungal decay were observed for the WPCs made with extracted wood, except for the pine WPCs, in which there was lower fungal decay from brown rot in the extracted wood samples. These results demonstrate that wood extractives affect the mechanical properties, water sorption, and fungal decay resistance of WPCs.

References

ASTM (2007a) Standard test method for preparation of extractive-free wood. ASTM D 1105-96. American Society for Testing and Materials, West Conshohocken, PA.nASTM (2007b) Standard test method for preparation of plastics. ASTM D 638-03. American Society for Testing and Materials, West Conshohocken, PA.nAWPA (2007) Standard method of testing wood preservatives by laboratory soil-block cultures. AWPA E10-06. American Wood Preservers' Association, Selma, AL.nBarnes RA, Gerber NN (1955) The antifungal agent from Osage-orange wood. J Am Chem Soc 77(12):3259-3262.nCarll CG, Highley TL (1999) Decay of wood and wood-based products above ground in buildings. J Test Eval 27 (2):150-158.nChang S-T, Wang S-Y, Kuo Y-H. (2003) Resources and bioactive substances from Taiwania (Taiwania cryptomerioides). J Wood Sci 49(1):1-4.nChoong ET, Achmadi SS (1991) Effect of extractives on moisture sorption and shrinkage in tropical woods. Wood Fiber Sci 23(2):185-196.nDawson-Andoh B, Matuana LM, Harrison J (2004) Mold susceptibility of rigid PVC/wood—flour composites. J Vinyl Addit Techn 10(4):179-186.nFengel D, Wegener G (1984) Wood: Chemistry, ultrastructure, reactions. Walter de Gruyter, Berlin, New York. 613 pp.nHillis WE (1970) Distribution, properties and formation of some wood extractives. Wood Sci Technol 5 (4):272-289.nKim J-W, Harper DP, Taylor AM (2008) Effect of wood species on water sorption and durability of wood—plastic composites. Wood Fiber Sci 40(4):519-531.nKim J-W, Harper DP, Taylor AM (2009) Effect of wood species on mechanical and thermal properties of wood—plastic composites. J Appl Polym Sci 112(3):1378-1385.nKoch P (1972) Utilization of southern pines. Vol I. The raw material. Agric Handbook No. 420. USDA For Serv Southern Forest Experimental Station. 734 pp.nKoch P (1985) Utilization of hardwoods growing on southern pine sites. Vol I. The raw material. Agriculture Handbook No. 605. USDA For Serv Southern Forest Experimental Station. 1418 pp.nLiu Y (2004) Study on the termiticidal components of Juniperus virginiana Chamaecyparis nootkatensis and Chamaecyparis lawsoniana. MS Thesis, Louisiana State University, Baton Rouge, LA.nLundin T (2001) Effect of accelerated weathering on the physical and mechanical properties of natural-fiber thermoplastic composites. MS Thesis, University of Wisconsin—Madison, Madison, WI.nMagel EA, Monties B, Drouet A, Jay-Allemand C, Ziegler H (1995) Heartwood formation: Biosynthesis of heartwood extractives and ‘secondary’ lignification. Pages 35-56 in H. Sandermann and M. Bonnet-Masimbert, eds. EUROSILVA—Contribution to forest tree physiology. INRA, Paris, France.nMaldas DC, Kamdem DP (1999) Wettability of extracted southern pine. Forest Prod J 49(11/12):91-93.nManning MJ, Ascherl F (2007) Wood-plastic composite durability and the compelling case for field testing. Pages 217-224 in Proc 9th International Conference on Wood & Biofiber Plastic composites. Forest Products Society, Madison, WI.nMantanis GI, Young RA, Rowell RM (1994) Swelling of wood: Part 1. Swelling in water. Wood Sci Technol 28 (2):119-134.nMantanis GI, Young RA, Rowell RM (1995) Swelling of wood. Part III. Effect of extractives on rate and maximum swelling. Holzforschung 49(3):239-248.nMcDaniel CA, Klocke JA, Baladrin MF (1989) Major antitermitic wood extractive components of Eastern redcedar, Juniperus virginiana. Mater Organismen 24(4):301-313.nMorrell JJ, Stark NM, Pendleton DE, McDonald AG (2006) Durability of wood—plastic composites. Wood Design Focus 16(3):7-10.nMorris PI, Cooper P (1998) Recycled plastic/wood composite lumber attacked by fungi. Forest Prod J 48(1):86-88.nNayer AN (1948) Swelling of wood in various organic liquids. PhD Thesis, University of Minnesota, Minneapolis, MN.nNearn WJ (1955) Effect of water-soluble extractives on the volumetric shrinkage and equilibrium moisture content of eleven tropical and domestic woods. Bull. 598. Penn State Univ Agric Exp Sta, University Park, PA. 38 pp.nNzokou P, Kamdem DP (2004) Influence of wood extractives on moisture sorption and wettability of red oak (Quercus ruba) black cherry (Prunus serotina) and red pine (Pinus resinosa). Wood Fiber Sci 36(4):483-492.nNzokou P, Kamdem DP (2005) X-ray photoelectron spectroscopy study of red oak (Quercus ruba) black cherry (Prunus serotina) and red pine (Pinus resinosa) extracted wood surfaces. Surf Interface Anal 37(8):689-694.nNussbaum RM, Sterley M (2002) The effect of wood extractive content on glue adhesion and surface wettability of wood. Wood Fiber Sci 34(1):57-71.nPendleton DE, Hoffard TA, Adcock T, Woodward B, Wolcott MP (2002) Durability of an extruded HDPE/wood composite. Forest Prod J 52(6):21-27.nRangaraj S, Smith LV (2000) Effect of moisture on durability of a wood/thermoplastic composite. J Thermoplast Compos 13(2):140-161.nRowe JW, Coner AN (1979) Extractives in eastern hardwoods—A review. General Technical Report FPL-18, USDA For Serv, Forest Products Laboratory, Madison, WI. 67 pp.nSaputra H, Simonsen J, Li K (2004) Effect of extractives on the flexural properties of wood/plastic composites. Compos Interface 11(7):515-524.nScheffer TC, Cowling E (1966) Natural resistance of wood to microbial deterioration. Ann Rev Phytopathol 4:147-170.nSchirp A, Wolcott MP (2005) Influence of fungal decay and moisture uptake on mechanical properties of extruded wood—plastic composites. Wood Fiber Sci 37(4):643-652.nSchultz TP, Harms WB, Fisher TH, McMurtrey KD, Minn J, Nicholas DD (1995) Durability of angiosperm heartwood: The importance of extractives. Holzforschung 49 (1):29-34.nSchultz TP, Nicholas DD (2000) Naturally durable heartwood: Evidence for a proposed dual defensive function of the extractives. Phytochemistry 54(1):47-52.nShen CH, Springer GS (1976) Moisture absorption and desorption of composite materials. J composite Mater 10 (1):2-20.nShi SQ, Gardner DJ (2006) Hygroscopic thickness swelling rate of compression molded wood fiberboard and wood fiber/polymer composites. Compos Part A-Appl S 37 (9):1276-1285.nSilva A, Freitag CM, Morrell JJ, Gartner B (2001) Effect of fungal attack on creep behavior and strength of wood plastic composites. Pages 73-77 in Proc 6th International Conference on Woodfiber—Plastic composites. Forest Products Society, Madision, WI.nSimpson W, TenWolde A (1999) Chapter 3. Physical properties and moisture relations of wood. In Wood handbook. General Technical Report 113. USDA For Serv, Forest Products Laboratory, Madison, WI. 463 pp.nSjöström E (1993) Wood chemistry: Fundamentals and application. 2nd ed. Academic Press, San Diego, CA. 293 pp.nSkaar C (1988) Wood—water relations. Springer-Verlag, Berlin, Germany. 282 pp.nSmith AL, Campbell CL, Walker DB, Hanover JW (1989) Extracts from black locust as wood preservatives: Extraction of decay resistance from black locust heartwood. Holzforschung 43(5):293-296.nSpalt HA (1957) The sorption of water by domestic and tropical woods. Forest Prod J 7(10):331-335.nSpalt HA (1979) Water-vapor sorption by wood of high extractive content. Pages 55-61 in Proc Wood Moisture Content, Temperature, and Humidity Relationship Symposium at Virginia Polytechnic Institute and State University, Blacksburg, VA.nStamm AJ, Loughborough WK (1942) Variation in shrinking and swelling of wood. Trans Am Soc Mech Eng 64:379-386.nSteckel V, Clemons CM, Thoemen H (2007) Effects of material parameters on the diffusion and sorption properties of wood-flour/polypropylene composites. J Appl Polym Sci 103(2):752-763.nSuchsland O (2004) The swelling and shrinkage of wood: A practical technology primer. Forest Products Society, Madison, WI. 189 pp.nTaylor AM, Gartner BL, Morrell JJ (2002) Heartwood formation and natural durability: A review. Wood Fiber Sci 34(4):587-611.nTaylor AM, Gartner BL, Morrell JJ, Tsunoda K (2006) Effects of heartwood extractive fractions of Thuja plicata and Chamaecyparis nootkatensis on wood degradation by termites or fungi. J Wood Sci 52(2):147-153.nTaylor FW (1974) Effect of extraction on the volume dimensions and specific gravity of solid wood blocks. Wood Sci 6(4):396-404.nVerhey SA, Laks PE, Richter DL (2001) Laboratory decay resistance of wood fiber/thermoplastic composites. Forest Prod J 51(9):44-49.nWang S, Hart JH (1983) Heartwood extractives of Maclura pomifera and their role in decay resistance. Wood Fiber Sci 15(4):290-301.nWang S, Hart JH, Behr EA (1976) Decay resistance of Osage-orange heartwood. For Prod Res Soc 30:22 [abstract].nWangaard FF, Granados LA (1967) The effect of extractives on water-vapor sorption by wood. Wood Sci Technol 1(4):253-277.nWolcott MP, Smith PM, Hermanson DJ (2005) Wood—plastic composites in emerging products and markets. Pages 335-343 in Proc 8th International Conference on Wood & Biofiber Plastic composites. Forest Products Society, Madison, WI.nYu X, Schmidt AR, Bello-Perez LA, Schmidt SJ (2008) Determination of the bulk moisture diffusion coefficient for corn starch using an automated water sorption instrument. J Agric Food Chem 56(1):50-58.n

Downloads

Published

2009-07-16

Issue

Section

Research Contributions