Chemical Composition of Cork from <i>Quercus Variablis</i>

Authors

  • Lei Yafang
  • Jia Ting
  • Song Xiaozhou

Keywords:

Cork, <i>Quercus variablis</i>, chemical composition, properties

Abstract

Cork is a natural and renewable raw material harvested from the outer bark of oak (Quercus spp.) trees. Unique and valuable properties of cork include low density, low permeability, high elasticity, good heat and acoustic insulation properties, and resistance to chemical and microbial attack. Chemical composition of cork is affected by many factors including the Quercus species and the number of times that cork has been harvested from the tree (ie virgin vs reproduction cork). Differences in chemical composition can significantly influence cork properties. In this study, chemical composition of virgin and reproduction cork from Quercus variablis trees in Shaanxi Province, China, was investigated. Cork samples were sequentially extracted with dichloromethane, ethanol, and water in a Soxhlet extractor. Eluted fractions were analyzed using ion chromatography. Chemical composition of virgin Q. variablis cork was 34.3% suberin, 20.6% lignin, 17.4% extractives, and 15.2% polysaccharides. Composition of reproduction cork was 36.9% suberin, 19.9% lignin, 12.7% extractives, and 12.0% polysaccharides. These results show that composition of virgin and reproduction Q. variablis cork was similar. Virgin Q. variablis cork had greater extractives and polysaccharides content than reproduction cork but a little less suberin. Chemical composition of Q. variablis cork from China is significantly different from that of Quercus suber L. cork from Europe.

References

Anjos O, Pereira H, Rosa M (2008) Effect of quality, porosity and density on the compression properties of cork. Holz Roh Werkst 66:295-301.nCaldas MM, Ferreira JL, Borges M (1986) Boletim do Institutodos Produtos Florestais. Cortica 578:339-342.nCastola V, Bighelli A, Rezzi S (2002) Composition and chemical variability of the triterpene fraction of dichloromethane extracts of cork (Quercus suber L.). Ind Crops Prod 15:15-22.nCastola V, Marongiu B, Bighelli A (2005) Extractives of cork (Quercus suber L.): Chemical composition of dichloromethane and supercritical CO2 extracts. Ind Crops Prod 21:65-69.nConde E, Cadahía E, Garcia-Vallejo MC, Gonzales-Adrados JR (1998) Chemical characterization of reproduction cork from spanish Quercus suber L. J Wood Chem Technol 18(4):447-469.nElvira C (1998) Chemical characterization of reproduction cork from Spanish Quercus suber L. J Wood Chem Technol 18(4):447-469.nGameiro CP, Cirne J, Gary G (2007) Experimental study of the quasi-static and dynamic behavior of cork under compressive loading. J Mater Sci 42:4316-4324.nGil AM (2000) An NMR microscopy study of water absorption in cork. J Mater Sci 35:1891-1900.nHolloway PJ (1972) The composition of suberin from the corks of Quercus suber L. and Betula pendula Roth. Chem Phys Lipids 9:158-170.nLiu Y (2008) Quercus variabilis B. cork structure and chemical composition analysis. MS thesis, Northwest A&F University, Shaanxi, China. 35 pp.nLiu Y, Zhao G (2004) Wooden resource materials. China Forestry Press, Beijing, China. 126 pp.nParameswaran N, Liese W, Giinzerodt H (1981) Characterization of wetcork in Quercus suber L. Holzforschung 35(4):195-199.nPereira H (1984) Chemical composition of virgin and reproduction cork of Quercus suber Boletim. Instituto dos Produtos Forestays, Portugal. Cortic 550:237-240.nPereira H (1988) Chemical composition and variability of cork from Quercus suber L. Wood Sci Technol 22:211-218.nPereira H, Meier D, Faix O (1996) Isolation and characterization of a guaiacyl lignin from saponified cork of Quercus suber L. Holzforschung 50(5):393-400.nSantos SA, Pinto PC, Silvestre AJ, Neto CP (2010) Chemical composition and antioxidant activity of phenolic extracts of cork from Quercus suber L. Ind Crop Prod 31:521-526. http://www.sciencedirect.com/science/article/pii/S0926669010000154-cor1#cor1 http://www.sciencedirect.com/science/article/pii/S0926669010000154-cor1#cor1'>http://www.sciencedirect.com/science/article/pii/S0926669010000154-cor1#cor1nSilva SP, Sabino MA, Fernandes EM (2005) Cork: Properties, capabilities and applications. Int Mater Rev 50(6): 345-365.nSousa AF, Pinto PR, Silvestre AD, Neto CP (2006) Triterpenic and other lipophilic compounds from industrial cork by-products. J Agric Food Chem 54:6888-6893.nWei X (2007) Chemical composition and its effect on properties of cork from three geographical areas. China Wood Industry 6:17-18.nZhang L (2009) Contents of the main chemical components of cork from variability. Journal of Northwestern Forestry University 24:163-165.nZheng Z (2005) Cork resources and utilization. Yunnan Forestry 3:23-24 [in Chinese with summary in English].n

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Published

2012-03-30

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Research Contributions