Improving the Color Stability of Wood-Plastic Composites Through Fiber Pre-Treatment
Keywords:
Wood-plastic composites, weathering, color, extractives, pigmentsAbstract
Wood-plastic composites (WPCs) continue to make inroads into the decking market. One of the main drawbacks from the consumer's perspective is that they can fade during weathering. It has been shown that WPCs fade more when exposed to a combination of light and water spray than when exposed only to light. This suggests that the loss of the color-imparting extractives from the wood could be partly to blame for color fade. Pigments are routinely added to only the plastic matrix to combat WPC color fade despite the fact that change in color could be due primarily to changes in the wood component of WPCs. In this study, we investigated two methods of fiber pretreatment in an attempt to improve the color stability of WPCs. The first was to remove water-soluble extractives from wood flour through a series of washes. Washed wood flour was then compounded with high-density polyethylene and injection-molded into test specimens. The second method involved coloring wood flour with either a water-based dye or an oil-based stain. Colored wood flour was also compounded with high-density polyethylene and injection-molded into test specimens. Pigments were added to half of the composites containing colored wood. The composites underwent accelerated weathering in a xenon-arc weathering apparatus, and were monitored for changes in color. Washing wood flour and coloring wood flour with a water-based dye were ineffective for improving composite color stability during weathering. However, coloring wood flour with an oil-based stain resulted in a more color stable WPC.References
American Society of Testing and Materials (ASTM) (2004) Standard Test Methods for Flexural Properties of Unreinforced and Reinforced Plastics and Electrical Insulating Materials. D 790 - 03. American Society for Testing and Materials, West Conshohocken, PAnAmerican Society of Testing and Materials (ASTM) (2004a) Xenon-arc exposure of plastics intended for outdoor applications. D 2565-99. American Society for Testing and Materials, West Conshohocken, PA.nBajwa D, Bruce D (2005) Improvements in the weathering characteristics of wood-plastic composites. Pages 187-190, in N. M. Stark, ed. Proc. 8th Inter Conf Woodfiber-Plastic Composites, May 23-25, 2005, Madison, WI. Forest Prod Soc, Madison WI.nClemons CM (2002) Wood-plastic composites in the United States: The interfacing of two industries. Forest Prod J 52(6):10-18.nClemons C, Stark N (2007) Use of salt cedar and Utah juniper as fillers in wood plastic composites. Res Paper FPL-RP-641 USDA Forest Prod Lab, Madison, WI.nColom X, Cañavate J, Pagès P, Saurina J, Carrasco F (2000) Changes in crystallinity of the HDPE matrix in composites with cellulosic fiber using DSC and FTIR. J Reinf Plast Comp 19(10):818-830.nFalk RH, Lundin T, Felton C (2000) The effects of weathering on wood-thermoplastic composites intended for outdoor applications, Pages 175-179 in Proc. Durability and Disaster Mitigation in Wood-Frame Housing, Nov 6-8, 2000, Madison, WI, Forest Prod Soc, Madison WI.nLundin T (2001) Effect of accelerated weathering on the physical and mechanical properties of natural-fiber thermoplastic composites. MS thesis, University of Wisconsin, Madison, WI.nMatuana LM, Kamdem DP (2002) Accelerated ultraviolet weathering of PVC/wood-flour composites. Polym Eng Sci 42(8):1657-1666.nMatuana LM, Kamdem DP, Zhang J (2001) Photoaging and stabilization of rigid PVC/wood-fiber composites. J Appl Polym Sci 80(11):1943-1950.nMuasher M, Sain M (2006) The efficacy of photostabilizers on the color change of wood filled plastic composites. Polym Degrad Stabil 91(5):1156-1165.nRobertson AR (1977) The CIE 1976 color-difference formulae. Color Res Appl 2(1):7-11.nRossi L (2005) WPCs: Putting innovation on a faster track. Pages 3-6 in N. M. Stark, ed. Proc. 8th Inter Conf Woodfiber-Plastic Composites, May 23-25, 2005, Madison, WI. Forest Prod Soc, Madison WI.nRowell RM, Lange SE, Jacobson RE (2000) Weathering performance of plant-fiber/thermoplastic composites. Mol Cryst Liq Cryst 353(1):85-94.nSeldén R, Nystrom B, Långström R (2004) UV aging of poly(propylene)/wood-fiber composites. Polym Composite 25(5):543-553.nStark NM (2006) Effect of weathering cycle and manufacturing method on performance of wood flour and high-density polyethylene composites. J Appl Polym Sci 100(4):3131-3140.nStark NM, Matuana LM (2003) Ultraviolet weathering of photostabilized wood-flour-filled high-density polyethylene composites. J Appl Polym Sci 90(10):2609-2617.nStark NM, Matuana LM (2004) Surface chemistry changes of weathered HDPE/wood-flour composites studied by XPS and FTIR spectroscopy. Polym Degrad Stabil 86(1):1-9.nStark NM, Matuana LM (2004a) Surface chemistry and mechanical property changes of wood-flour/high-density-polyethylene composites after accelerated weathering. J Appl Polym Sci 94(6):2263-2273.nStark NM, Matuana LM (2006) Influence of photostabilizers on wood flour-HDPE composites exposed to xenon-arc radiation with and without water spray. Polym Degrad Stabil 91(2):3048-3056.nStark NM, Matuana LM, Clemons CM (2004) Effect of processing method on surface and weathering characteristics of wood-flour/HDPE composites. J Appl Polym Sci 93(3): 1021-1030.n
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