Wood Polymer Composites

Authors

  • Marc H. Schneider

Keywords:

Wood polymer composites, WPC, wood polymer combinations, acrylic wood, impregnated wood, stabilized wood, modified wood

Abstract

This paper is an update of several earlier review articles on wood polymer composites (WPC). Notable polymer types that have been used to make WPC are phenol-formaldehyde (PF), various vinyls, and furfuryl alcohol. Phenol-formaldehyde and similar chemicals typically enter wood cell walls, whereas the vinyls usually fill cell lumens. Combination treatments that modify both lumens and walls are possible. Diffusion and mass flow are two possible methods of introducing the chemical into the wood. Curing can be accomplished using a catalyst and heat or penetrating radiation. Type of treating chemical and final density are major determinants of WPC properties. Physical and mechanical properties of WPC have been extensively studied. Major WPC improvements over untreated wood are in hardness, finishability, and dimensional stability. There is much yet to be learned about chemical formulations, treating and curing, and their relationships to property enhancements, WPC recyclability, and chemicals from renewable sources for making WPC.

References

Autio, T., and J. K. Miettinen. 1970. Experiments in Finland on properties of wood-polymer combinations. Forest Prod. J. 20(3):36-42.nBeall, F. C., J. A. Meyer, and C. Skaar. 1966. Direct and RF heating of wood-plastic composites. Forest Prod. J. 16(9):99-106.nBeall, F. C., A. E. Witt, and L. R. Bosco. 1973. Hardness and hardness modulus of wood-polymer composites. Forest Prod. J. 23(1):56-60.nBoey, F. Y. C. 1989. Nonlinear creep deformation analysis of a radiation-cured wood polymer composite. Composites Sci. Technol. 35(3):257-272.nBrebner, K. I. 1989. Method of surface impregnation of wood articles and wood articles made therewith. U.S. Patent No. 4,883,719.nBrebner, K. I., and M. H. Schneider. 1985. Wood-polymer combinations: Bonding of alkoxysilane coupling agents to wood. Wood Sci. Technol. 19:67-73.nBrebner, K. I., M. H. Schneider, and R. T. Jones. 1988. The influence of moisture content on the flexural strength of styrenepolymerized wood. Forest Prod. J. 38(4):55-58.nBrebner, K. I., M. H. Schneider, and L. E. St. Pierre. 1985. Flexural strength of polymer-impregnated eastern white pine. Forest Prod. J. 35(2):22-27.nBryant, B. S. 1966. The chemical modification of wood from the point of view of wood science and economics. Forest Prod. J. 16(2):20-27.nFuruno, T., and T. Goto. 1970. The penetration of MMA monomer into hinoki. Mokuzai Gakkaishi 16(5):201-208. (Canada Dept. of the Secretary of State, Foreign Languages Division Translation No. 0687, 1971.)nFuruno, T., and T. Goto. 1973. The penetration of MMA monomer into the woody cell wall. Mokuzai Gakkaishi 19(6):271-274.nGoldstein, I. S., and W. E. Loos. 1973. Special treatments. Pages 341-371 in D. D. Nicholas, ed. Wood deterioration and its prevention by preservative treatments, vol. 1: Degradation and protection of wood. Syracuse University Press, Syracuse, NY.nHartley, I. D., and M. H. Schneider. 1992. Water vapour diffusion and adsorption characteristics of sugar maple (Acer saccharum Marsh.) wood polymer composites. Wood Sci. Technol. (in press).nHartman, S. 1969. Modified wood with aqueous polyurethane systems. Forest Prod. J. 19(5):39-42.nHills, P. R. 1972. Radiation polymerized composites based on wood: New materials for use in corrosive environments. Composites Sept.:211-215.nIannazzi, F. D., P. L. Levins, F. G. Perry, and R. S. Lindstrom. 1964. Technical and economic considerations for an irradiated wood-plastic material. U.S. Atomic Energy Commission, Division of Technical Information Report No. TID-21434. 93 pp.nLangwig, J. E., J. A. Meyer, and R. W. Davidson. 1968. Influence of polymer impregnation on mechanical properties of basswood. Forest Prod. J. 18(7):33-36.nLangwig, J. E., J. A. Meyer, and R. W. Davidson. 1969. New monomers used in making wood-plastics. Forest Prod. J. 19(11):57-61.nLoos, W. E., and G. L. Robinson. 1968. Rates of swelling of wood in vinyl monomers. Forest Prod. J. 18(9):109-112.nMacLean, J. D. 1960. Preservative treatment of wood by pressure methods. USDA Handbook No. 40. U.S. Government Printing Office, Washington, DC.nMathias, L. J., and J. R. Wright. 1989. New wood-polymer composites: Impregnation and in situ polymerization of hydroymethacrylates. Polymer Reprints 30(1):233-234.nMeyer, J. A. 1965. Treatment of wood-polymer systems using heat-catalyst technique. Forest Prod. J. 15(9):362-364.nMeyer, J. A. 1968. Crosslinking affects sanding properties of wood plastic. Forest Prod. J. 18(5):89.nMeyer, J. A. 1982. Industrial use of wood polymer materials: State of the art. Forest Prod. J. 32(1):24-29.nMeyer, J. A. 1984. Wood-polymer materials. Pages 257-289 in R. M. Rowell, ed. The chemistry of solid wood. ACS Advances in Chemistry Series 207.nMeyer, J. A. 1987. Wood polymer composites. Technologist 1(3):4-7.nMoore, G. R., D. E. Kline, and P. R. Blankenhorn. 1983. Impregnation of wood with a high-viscosity epoxy resin. Wood Fiber Sci. 15(3):223-234.nNicholas, D. D., and J. F. Siau. 1973. Factors influencing the treatability of wood. Ch. 4 in D. D. Nicholas, ed. Wood deterioration and its prevention by preservative treatments, vol. 2. Syracuse University Press, Syracuse, NY.nRaech, H., Jr. 1965. Allylic resins and monomers. Reinhold plastics applications series, Reinhold Publishing Corporation, New York, NY. 223 pp.nRosen, H. N. 1974. How craftsmen and home hobbyists can make wood plastic composite materials. USDA Gen. Tech. Rep. NC-10. 9 pp.nRosen, H. N. 1976. Moisture adsorption and swelling in polyethylene glycol and polymethyl methacrylate treated wood at high relative humidity. Wood Fiber 7(4):249-255.nRowell, R. M. 1983. Bioactive polymer-wood composites. Pages 347-357 in T. J. Roseman and S. Z. Mansdorf, eds. Controlled release delivery systems. Marcel Dekker Inc., New York, NY.nRowell, R. M., and P. Konkol. 1987. Treatments that enhance physical properties of wood. U.S. Forest Products Laboratory General Technical Report FPL-GTR-55. 12 pp.nRowell, R. M., and R. L. Youngs. 1981. Dimensional stabilization of wood in use. U.S. Forest Products Laboratory Research Note FPL-0243. 8 pp.nRowell, R. M., R. Moisuk, and J. A. Meyer. 1982. Wood-polymer composites: Cell wall grafting with alkylene oxides and lumen treatments with methyl methacrylate. Wood Science 15(2):90-96.nSchaudy, R., and E. Proksch. 1982. Wood plastic combinations with high dimensional stability. Ind. Eng. Chem. Prod. Res. Dev. 21(3):369-375.nSchneider, M. H. 1993. Unpublished results of laboratory research.nSchneider, M. H., and K. I. Brebner. 1985. Wood-polymer combinations: The chemical modification of wood by alkoxysilane coupling agents. Wood Sci. Technol. 19:67-73.nSchneider, M. H., and J. G. Phillips. 1991. Elasticity of wood and wood polymer composites in tension, compression and bending. Wood Sci. Technol. 25:361-364.nSchneider, M. H., J. G. Phillips., D. A. Tingley, and K. I. Brebner. 1989. Toughness of polymer impregnated sugar maple at two moisture contents. Forest Prod. J. 39(6):11-14.nSchneider, M. H., J. G. Phillips, D. A. Tingley, and K. I. Brebner. 1990. Mechanical properties of polymer-impregnated sugar maple. Forest Prod. J. 40(1):37-41.nSchneider, M. H., K. I. Brebner, and I. D. Hartley. 1991. Swelling of a cell lumen filled and cell-wall bulked wood polymer composite in water. Wood Fiber Sci. 23(2):165-172.nSiau, J. F. 1969. The swelling of basswood by vinyl monomers. Wood Sci. 1(4):250-253.nSiau, J. F. 1984. Transport processes in wood. Springer-Verlag, Berlin, Germany. 245 pp.nSiau, J. F., and J. A. Meyer. 1966. Comparison of the properties of heat and radiation cured wood-polymer composites. Forest Prod. J. 16(8):47-56.nSiau, J. F., J. A. Meyer, and C. Skaar. 1965. Wood-polymer combinations using radiation techniques. Forest Prod. J. 15(10):426-434.nSiau, J. F., J. A. Meyer, and R. S. Kulik. 1972. Fire-tube tests of wood-polymer composites. Forest Prod. J. 22(7):31-36.nSordo, J. J. L. E. 1975. Breve Estudio de los Parametros de Procesamiento y de Formulacion para llever a cabo la Impregnacion de Maderas con Monomeros Vanilicos en la Planta Piloto del Laboratorio de Ingenieria Quimica. Tesis Profesional, Facultad de Quimica, Universidad Nacional Autonoma de Mexico. 227 pp.nStamm, A. J. 1964. Wood and cellulose science. Ronald Press, New York, NY. 549 pp.nStamm, A. J. 1977a. Dimensional changes of wood and their control. Pages 115-139 in I. S. Goldstein, ed. Wood technology: Chemical aspects. ACS Symposium Series 43. American Chemical Society, Washington, DC. 372 pp.nStamm, A. J. 1977b. Dimensional stabilization of wood with furfural alcohol resin. Pages 115-139 in I. S. Goldstein, ed. Wood technology: Chemical aspects. ACS Symposium Series 43. American Chemical Society, Washington, DC. 372 pp.nWitt, A. E. 1981. Acrylic wood in the United States. Radiat. Phys. Chem. 18(1-2):67-80.nYoung, R. A., and J. A. Meyer. 1968. Heartwood and sapwood impregnations with vinyl monomers. Forest Prod. J. 18(4):66-68.n

Downloads

Published

2007-06-22

Issue

Section

Research Contributions