Equilibrium Moisture Content of Wood in High-Temperature Pressurized Environments

Authors

  • Christopher A. Lenth
  • Frederick A. Kamke

Keywords:

EMC (equilibrium moisture content), wood, thermal degradation, high-temperature, sorption

Abstract

Experiments were conducted on the water sorption characteristics of three wood species, for both juvenile wood and mature wood, at conditions above and below 100°C. A pressurized chamber was constructed for this purpose. At 50°C, equilibrium moisture content (EMC) behavior deviated only slightly from predictions based on the published data for Sitka spruce. At 160°C, the sorption behavior was distinctly different from the 50°C data, or any extrapolation from published low-temperature data. The data suggested that a change in the sorptive properties of the wood occurred as temperature and moisture conditions exceeded the glass transition temperature for lignin. At 50°C, juvenile wood tended to equilibrate at a higher moisture content than mature wood. At 160°C, however, juvenile wood exhibited a markedly lower EMC than mature wood. Thermal degradation of wood was detected during the experiments. Reduction in the sorptive behavior as a result of thermal degradation is proposed as a possible explanation for differences in EMC behavior for juvenile and mature wood at 160°C.

References

Aklonis, J. J., and W. J. MacNight. 1983. Introduction to polymer viscoelasticity. J. Wiley and Sons, New York, NY.nAvramidis, S. 1989. Evaluation of "three-variable" models for the prediction of equilibrium moisture content in wood. Wood Sci. Technol.23:251-258.nCasey, L. J. 1987. Changes in wood-flake properties in relation to heat, moisture and pressure during flakeboard manufacture. M.S. Thesis, V.P.I. & S.U. Blacksburg, VA.nChristensen, G. N., and K. E. Kelsey. 1959. The sorption of water vapor by the constituents of wood. Holz Roh- Werkstoff.17(5):89-204.nEngelhardt. F. 1979. Investigations on the sorption of water vapour by beech at temperatures ranging from 110 to 170°C. Holz Roh- Werkstoff.37(3):99-112.nFengel, D., and G. Wegener. 1989. Wood: Chemistry, ultrastructure, reactions. Walter de Gruyter, New York, NY.nGeimer, R., R. J. Mahoney, S. P. Loehnertz, and R. W. Meyer. 1985. Influence of processing-induced damage on strength of flakes and flakeboards. Res. Paper#463. USDA Forest Prod. Lab., Madison, WI.nGrumach, M. 1951. The equilibrium moisture content of wood in superheated steam. CSIRO, Melbourne, Australia. Div. For. Prod., Proj. S 17 Prog. Rep.nHann, R. A. 1966. Theoretical considerations in the drying of wood at pressures above atmospheric. Forest. Prod. J.16(4):25-32.nHailwood, A. J., and S. Horrobin. 1946. Absorption of water by polymers: Analysis in terms of a simple model. Trans. Faraday Soc.42B:84-102.nHillis, W. E. 1984. High temperature and chemical effects on wood stability. Part I: General considerations. Wood Sci. Technol.18:281-293.nHsu, W. E., W. Schwald, J. Schwald, and J. A. Shields. 1988. Chemical and physical changes required for producing dimensionally stable wood-based composites. Wood Sci. Technol.22:281-289.nHumphrey, P. E., and A. J. Bolton. 1989. The hot pressing of dry-formed wood-based composites Part II. A simulation model for heat and mass transfer, and typical results. Holzforschung.43(3):199-206.nJeffries, R. 1960. The sorption of water by cellulose and eight other textile polymers. Part III. The sorption of water vapor by textile polymers at 120°C and 150°C. J. Text. Inst.51(11):T441.nKamke, F. A., and L. J. Casey. 1989. Fundamentals of flakeboard manufacture: Internal mat conditions. For. Prod. J.38(6):38-44.nKamke, F. A., and M. P. Wolcott. 1991. Fundamentals of flakeboard manufacture: Wood-moisture relationships. Wood Sci. Technol.25:57-71.nKamke, F. A., and S. E. Johnson. 1994. Phenolic resin interaction during steam-injection pressing of flakeboard. In C-Y Hse, B. Tomita, and S. J. Branham, eds. Proc. Adhesives and Bonded Wood Symposium, Nov. 19-21, 1991, Seattle, WA. Forest Products Research Society, Madison, WI.nKaar, W. E., L. G. Cool, M. M. Merriman, and D. L. Brink. 1991. The complete analysis of wood polysaccharides using HPLC. J. Wood Chem. Tech.11(4):447-463.nKauman, W. G. 1956. Equilibrium moisture content and drying control in superheated steam drying. Forest Prod. J.6(9):328-332.nKelly, S. S., T. G. Rials, and W. G. Glasser. 1987. Relaxation behavior of the amorphous components of wood. J. Mater. Sci.22:617-624.nKeylwerth, R. 1949. Fundamentals of high-temperature drying of wood. Holz Zentrabl.75(76):953-954.nKohlman, F., and L. Malmquist. 1952. Research on seasoning sawn pine timber at high temperatures. Medd. Sven. Traforskn. Inst. Avd. 23.nKretschmann, D. E., and B. A. Bendsten. 1992. Ultimate tensile stress and modulus of elasticity of fast-grown plantation loblolly pine lumber. Wood Fiber Sci.24(2):189-203.nLadell, J. L. 1957. High temperature kiln drying of eastern Canadian softwoods. West. For. Prod. Lab. Tech. Note 2. Vancouver, BC., Can.nLutz, J. F. 1974. Drying of veneer to a controlled moisture content by hot-pressing and steaming. USDA Forest Serv. Res. Pap. FPL 227. Forest Prod. Lab., Madison, WI.nNeter, J., and W. Wasserman. 1974. Applied linear statistical models. Richard D. Irwin Inc., Homewood, IL.nPanshin, A. J., and C. De Zeeuw. 1980. Textbook of wood technology. McGraw-Hill Co. New York, NY.nPrice, E. W. 1976. Determining tensile properties of sweetgum veneer flakes. Forest Prod. J.26(10):50-53.nResch, H., M. L. Hoag, and H. N. Rosen. 1988. Desorption of yellow poplar in superheated steam. Forest Prod. J.38(3):13-18.nRosen, H. N. 1980. Psychrometric relationships and equilibrium moisture content of wood at temperatures above 212 F. Wood Fiber12(3):153-171.nSiau, J. F. 1971. Flow in wood. Syracuse University Press, Syracuse, NY.nSiau, J. F. 1984. Transport processes in wood. Springer-Verlag, New York, NY.nSiau, J. F. 1995. Wood: influence of moisture on physical properties. Dept. Wood Sci. and For. Prod. Blacksburg, VA.nSimpson, W. T. 1971. Equilibrium moisture content prediction for wood. Forest Prod. J.21(5):48-49.nSimpson, W. T. 1973. Predicting equilibrium moisture content of wood by mathematical models. Wood Fiber5(1):41-49.nSimpson, W. T. 1980. Sorption theories applied to wood. Wood Fiber12(3):183-195.nSimpson, W. T., and H. N. Rosen. 1981. Equilibrium moisture content of wood at high temperatures. Wood Fiber13(3):150-158.nSkaar, C. 1972. Water in wood. Syracuse University Press, Syracuse, NY.nSkaar, C. 1976. Pages 113-127 in C. C. Gerhards, and J. M. McMillan, eds: High-temperature drying effects on mechanical properties of softwood lumber. USDA Forest Serv., Forest Prod. Lab., Madison, WI.nSkaar, C. 1988. Wood-water relations. Springer-Verlag, New York, NY.nStrickler, M. D. 1968. High temperature relations of grand fir. Forest Prod. J.18(4):69-75.nSturany, H. 1952. The Schilde air-free steam dryer for wood. Holz Roh- Werkst.10:358-362.nUrquhart, A. R., and A. M. Williams. 1924. The moisture relations of cotton: the effect of temperature on the absorption of water by soda-boiled cotton. J. Text. Inst.15:T559.nU.S. Forest Products Laboratory. 1999. Wood handbook: Wood as an engineering material. Forest Prod. Lab., Gen. Tech. Rep. FPL-GTR-113, Forest Prod. Lab., Madison, WI.n

Downloads

Published

2007-06-05

Issue

Section

Research Contributions