Temperature Dependency of Bond Strength of Polyvinyl Acetate Emulsion Adhesives for Wood
Keywords:
Temperature dependency, adhesives, bond strengthAbstract
Bond strengths of PVAc emulsion adhesives were evaluated in the range from -130 to 140 C in both tensile shear and tensile cross-lap joints of wood. Both shear and tension bond strengths strongly depended on rheological properties and tensile strengths of adhesives over the entire temperature range, and the maximum peaks of each bond strength and the film strength were observed around the Tg of PVAc. Higher shear bond strengths were observed in the lower temperature range, while the other bond strengths declined markedly. This phenomenon was explained by the possible occurrence of mechanical interlocking at wood surface and difference of its effectiveness with the direction of stress on the joint. Furthermore, a high amount of grafting effectively fortified both the bond and film strengths of adhesives throughout the temperature range investigated.References
Angelo, R. J., R. M. Ikeda, and M. L. Wallach. 1965. Multiple glass transitions of block polymers. Polymer6(3):141-156.nBergin, E. G., and S. Chow. 1974. Softening temperature, ash content, and bond quality of polyvinyl-acetate-emulsion adhesives. For. Prod. J.24(11):45-49.nBradford, E. B., and J. Vanderhoff. 1972. Additional studies of morphological changes in latex films. J. Macromol. Sci.-Phys.B6(4):671-694.nChow, S. 1973. Softening temperatures and durability of wood adhesives. Holzforschung27(2):64-68.nFukuzawa, K. 1969. Studies on rheology of pressure sensitive adhesion tapes. J. Adhesion Soc. Japan5(5):294-301.nGent, A. N., and R. P. Petrich. 1969. Adhesion of viscoelastic materials to rigid substrates. Proc. Roy. Soc.A310:433-448.nKaelble, D. H. 1969. Peel adhesion: Influence of surface energies and adhesive rheology. J. Adhesion1:102-122.nMarra, A. A. 1955a. A new method for testing wood adhesives: I. The specimen. For. Prod. J.5:301-306.nMarra, A. A. 1955b. A new method for testing wood adhesives: II. Test apparatus. For. Prod. J.5:385-388.nMarra, A. A. 1955c. A new method for testing wood adhesives: III. Response of the cross-lap specimen to joint defects. For. Prod. J.6:142-148.nMizumachi, H., Y. Hatano, S. Kamei, and Y. Yamagishi. 1979. Physical properties of ethylene/vinyl acetate copolymers and the bond strength. Mokuzai Gakkaishi25(4):288-295.nMizumachi, H., Y. Hatano, and Y. Yamagishi. 1980. Influence of the mechanical properties of polymer blends with complete miscibility on wood adhesion. Holzforschung34(5):169-173.nMotohashi, K., and B. Tomita. 1979. The relation between properties of poly(vinyl acetate) emulsion and tensile strength for the cross-lap joint. Mokuzai Gakkaishi25(3):225-232.nMotohashi, K., and B. Tomita. 1980. Dynamic viscoelasticity of wood-PVAc emulsion composites. Mokuzai Gakkaishi26(2):87-96.nMotohashi, K., B. Tomita., and H. Mizumachi. 1982. Relationship between chemical properties of poly(vinyl acetate) emulsion adhesives and tensile strength for cross-lap joint of wood. Holzforschung36(4):183-189.nNielsen, L. E. 1975. Mechanical properties of polymers and composites. Marcel Dekker Inc., New York.nSteiner, P. R., and S. Chow. 1975. Low-temperature durability of common wood adhesives. For. Prod. J.25(8):26-30.nUchida, T., T. Soen, T. Inoue, and H. Kawai. 1972. Domain structure and bulk properties of solvent-cast films of A-B-A block copolymers of styrene-isoprene-styrene. J. Polym. Sci. Part A-210:101-121.n
Downloads
Published
Issue
Section
License
The copyright of an article published in Wood and Fiber Science is transferred to the Society of Wood Science and Technology (for U. S. Government employees: to the extent transferable), effective if and when the article is accepted for publication. This transfer grants the Society of Wood Science and Technology permission to republish all or any part of the article in any form, e.g., reprints for sale, microfiche, proceedings, etc. However, the authors reserve the following as set forth in the Copyright Law:
1. All proprietary rights other than copyright, such as patent rights.
2. The right to grant or refuse permission to third parties to republish all or part of the article or translations thereof. In the case of whole articles, such third parties must obtain Society of Wood Science and Technology written permission as well. However, the Society may grant rights with respect to Journal issues as a whole.
3. The right to use all or part of this article in future works of their own, such as lectures, press releases, reviews, text books, or reprint books.